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The (CH2Br)4 cavitand 1 and its reactions with NaOAc in varying stoichiometric ratios have been used to prepare a series of five different (CH2OAc)4−n(CH2Br)n cavitands (n = 0−3) 2−6 with mixed substituents, which can be separated by column chr
Publikováno v:
ChemInform. 33
Autor:
Manuela Flauaus, Stefan Immel, Björn Corzilius, Klaus-Peter Dinse, Rüdiger-A. Eichel, Herbert Plenio, Dominik Stumm, A. Gembus
Publikováno v:
The journal of physical chemistry. B. 110(30)
The double-bridged hemicarcerand [A,B-(CH2OH)2-cavitand]-(CH2NHCH2)2-[A,B-(CH2OH)2-cavitand] 23 (and several other related compounds) was synthesized by the condensation of the two complementary precursors A,B-(CH2NH2)2(CH2OH)2-cavitand and A,B-(CH2B