Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Manuel Nappi"'
Publikováno v:
Chemical Science. 13:6982-6989
Alcohols are among the most widely occurring functional groups found in naturally abundant, biologically relevant organic compounds, which in many cases are considered feedstock chemicals. Herein, we report a metal-free method for the deoxygenative c
Autor:
Matthew J. Gaunt, Vivian M. Lechner, Manuel Nappi, Patrick J. Deneny, John C. K. Chu, Sarah Folliet
Publikováno v:
Chemical Reviews. 122:1752-1829
Chemically modified biomacromolecules─i.e., proteins, nucleic acids, glycans, and lipids─have become crucial tools in chemical biology. They are extensively used not only to elucidate cellular processes but also in industrial applications, partic
Autor:
Jesus Rodrigalvarez, Hiroki Azuma, Matthew J. Gaunt, Matthew E. Burns, Manuel Nappi, Nils J. Flodén
Publikováno v:
Nature Chemistry. 12:76-81
The development of robust catalytic methods to assemble tertiary alkylamines provides a continual challenge to chemical synthesis. In this regard, transformation of a traditionally unreactive C-H bond, proximal to the nitrogen atom, into a versatile
Publikováno v:
J Am Chem Soc
[Image: see text] Selective chemistry that modifies the structure of DNA and RNA is essential to understanding the role of epigenetic modifications. We report a visible-light-activated photocatalytic process that introduces a covalent modification at
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c5167dbf15ba77b5ef1a6dc8514bf2c3
https://www.repository.cam.ac.uk/handle/1810/312896
https://www.repository.cam.ac.uk/handle/1810/312896
Selective chemistry that modifies the structure of DNA and RNA is essential to understanding the role of epigenetic modifications. We report a visible-light-activated photocatalytic process that introduces a covalent modification at a C(sp3 )–H bon
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cd2aff78806cdc49c87134100b87413
https://doi.org/10.26434/chemrxiv.12981725
https://doi.org/10.26434/chemrxiv.12981725
Autor:
Matthew J. Gaunt, Manuel Nappi
Publikováno v:
Organometallics. 38:143-148
This article presents a new class of mild reagents that is capable of oxidizing palladacycle(II) complexes to high-valent palladium species, promoting the formation of C–N bonds in stoichiometric a...
Publikováno v:
Angewandte Chemie. 130:3232-3236
A palladium(II)-catalyzed γ-C-H amination of cyclic alkyl amines to deliver highly substituted azetidines is reported. The use of a benziodoxole tosylate oxidant in combination with AgOAc was found to be crucial for controlling a selective reductive
Autor:
Jesus, Rodrigalvarez, Manuel, Nappi, Hiroki, Azuma, Nils J, Flodén, Matthew E, Burns, Matthew J, Gaunt
Publikováno v:
Nature chemistry. 12(1)
The development of robust catalytic methods to assemble tertiary alkylamines provides a continual challenge to chemical synthesis. In this regard, transformation of a traditionally unreactive C-H bond, proximal to the nitrogen atom, into a versatile
Publikováno v:
Angewandte Chemie (International ed. in English). 57(12)
A palladium(II)-catalyzed γ-C-H amination of cyclic alkyl amines to deliver highly substituted azetidines is reported. The use of a benziodoxole tosylate oxidant in combination with AgOAc was found to be crucial for controlling a selective reductive
Publikováno v:
Angewandte Chemie International Edition