Photoactivation of titanium-oxo cluster [Ti 6 O 6 (OR) 6 (O 2 C ^t Bu) 6 ]: mechanism, photoactivated structures, and onward reactivity with O 2 to a peroxide complex.

Autor: Brown SE; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Mantaloufa I; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Andrews RT; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Barnes TJ; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Lees MR; Department of Physics, University of Warwick Coventry UK., De Proft F; Research Group of General Chemistry (ALGC), Vrije Universiteit Brussel (VUB) Brussels Belgium ana.cunha@uantwerpen.be., Cunha AV; Research Group of General Chemistry (ALGC), Vrije Universiteit Brussel (VUB) Brussels Belgium ana.cunha@uantwerpen.be.; University of Antwerp Antwerp Belgium., Pike SD; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk.

Publikováno v: Chemical science [Chem Sci] 2022 Dec 07; Vol. 14 (3), pp. 675-683. Date of Electronic Publication: 2022 Dec 07 (Print Publication: 2023).