Zobrazeno 1 - 10
of 52
pro vyhledávání: '"Manganocene"'
Akademický článek
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Publikováno v:
Physical chemistry chemical physics : PCCP. 21(44)
Manganocene [Mn(C5H5)2], a 17-electron system, is expected to have a high electron affinity, as addition of an extra electron would make it a closed-shell 18-electron system. Surprisingly, it has a very low electron affinity of only 0.28 eV. Combined
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::624055149023db504b75234a544d439d
https://pubmed.ncbi.nlm.nih.gov/31524210
https://pubmed.ncbi.nlm.nih.gov/31524210
Autor:
Ricardo Inostroza-Rivera, Arindam Chakraborty, G. Naaresh Reddy, Santanab Giri, Rakesh Parida
Publikováno v:
Journal of molecular modeling. 25(8)
A new magnetic superalkali/superhalogen molecule based on the sandwich complex manganocene is reported. The hydrogen atoms of the cyclopentadienyl rings are periodically substituted with electron-donating and electron-withdrawing ligands (or both) to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6432b163e8ce4bfcef8acf291583f707
https://pubmed.ncbi.nlm.nih.gov/31292761
https://pubmed.ncbi.nlm.nih.gov/31292761
Publikováno v:
Organometallics. 35:1986-1994
The first preparations of half-open and open manganocenes were accomplished. Treatment of KPdl′ (Pdl′ = 2,4-(Me3C)2C5H5)) with [{(η5-Cp”)Mn(thf)(μ-I)}2] (Cp″ = 1,2,4-(Me3C)3C5H2) and MnI2(thf)2 resulted in the formation of [(η5-Cp″)Mn(Pd
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5f3ed9d3006d0fe68235e855c5b36ca0
https://doi.org/10.1021/acs.organomet.6b00281
https://doi.org/10.1021/acs.organomet.6b00281
Publikováno v:
Journal of Chemical Information and Modeling
Although the unusual structural, magnetic,electronic, and spin characteristics of manganocene hasintrigued scientists for decades, a unified explanation andrationalization of its properties has not yet been provided.Results obtained by Multidetermina
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::15936e837988fd1d6328f21927799ae8
https://pubmed.ncbi.nlm.nih.gov/30658036
https://pubmed.ncbi.nlm.nih.gov/30658036
Autor:
Michael Bodensteiner, Charlene A. Smith, David Collison, Madeleine Helliwell, Floriana Tuna, Richard A. Layfield
Publikováno v:
Dalton Trans.. 42:71-74
The trimetallic complex [{CpMn(μ-OSiPh3)2}2Mn] (1) and the heterocubane [CpMn(μ3-SSiPh3)]4 (2) are formed by deprotonation of Ph3SiQH (Q = O, S) by manganocene, or by transmetallation of manganocene by Ph3SiQLi. The Mn(II) centres in 1 and 2 are an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::37450a6547b865835f77844e324f35eb
https://doi.org/10.1039/c2dt32262e
https://doi.org/10.1039/c2dt32262e
Akademický článek
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Akademický článek
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Autor:
Jeremy M. Rawson, Carmen Soria Alvarez, Richard A. Layfield, Andrew E. H. Wheatley, Mary McPartlin, Jonathan C. Burley, Richard A. Kowenicki, Paul T. Wood, Sally R. Boss, Simon M. Humphry, Dominic S. Wright
Publikováno v:
Dalton Trans.. :3481-3487
Manganocene, Cp2Mn, has been employed as a precursor in the synthesis of a range of Mn(II) dimers of the type [CpMn(μ-X)]2 [X = 8-NHC9H6N (1), N(Ph)(C5H4N) (2), N(4-EtC6H4)(C5H4N) (3) and CCPh (4)] as well as the bis-adduct [Cp2Mn{HNC(NMe2)2}2] (5).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::da59bc7edcbed4bebbdd63e740a2947d
https://doi.org/10.1039/b409135c
https://doi.org/10.1039/b409135c
Autor:
Achim Elvers, Ulrich Zenneck, Timothy Clark, Matthias Zeller, Matthias Hennemann, Frank W. Heinemann
Publikováno v:
Angewandte Chemie International Edition. 39:2087-2091
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2431420d37ccea14fcef454a7e974504
https://doi.org/10.1002/1521-3773(20000616)39:12<2087::aid-anie2087>3.0.co
https://doi.org/10.1002/1521-3773(20000616)39:12<2087::aid-anie2087>3.0.co