Zobrazeno 1 - 10
of 659
pro vyhledávání: '"Manfred, Scheer"'
Autor:
Dr. Thomas M. Rookes, Dr. Gábor Balázs, Dr. Benedict M. Gardner, Dr. Ashley J. Wooles, Prof. Dr. Manfred Scheer, Prof. Dr. Stephen T. Liddle
Publikováno v:
ChemistryEurope, Vol 1, Iss 3, Pp n/a-n/a (2023)
Abstract Structurally characterised U−Sb bonds are rare. Here, the synthesis and characterisation of [U(TrenDMBS){Sb(H)C(H)(SiMe3)2}] (5, TrenDMBS=N(CH2CH2NSiMe2But)3) and [{U(TrenTIPS)}2{Sb3(μ6‐Li)(μ‐Li[THF]2)3Sb3}] (6, TrenTIPS=N(CH2CH2NSiP
Externí odkaz:
https://doaj.org/article/8773be8400a94bb3addec29c1816cd09
Autor:
Mehdi Elsayed Moussa, Susanne Bauer, Christian Graßl, Christoph Riesinger, Gábor Balázs, Manfred Scheer
Publikováno v:
Molecules, Vol 29, Iss 9, p 2025 (2024)
Phosphorus- and arsenic-containing cobalt clusters are an interesting class of compounds that continue to provide new structures with captivating bonding patterns. Although the first members of this family were reported 45 years ago, the number of su
Externí odkaz:
https://doaj.org/article/caf29e77bfbd4fb7bc2c61ae7a24489b
Publikováno v:
Inorganics, Vol 11, Iss 10, p 377 (2023)
A new synthetic pathway to various mono-alkyl-substituted phosphinoboranes HRP–BH2–NMe3 has been developed. The new synthetic route starting from alkyl halides and NaPH2 followed by metalation and salt metathesis is performed in a one-pot procedu
Externí odkaz:
https://doaj.org/article/ca101e60ca84479db2f58325912121f6
Autor:
Stephan Reichl, Eric Mädl, Felix Riedlberger, Martin Piesch, Gábor Balázs, Michael Seidl, Manfred Scheer
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
Asymmetrically substituted phosphine ligands play a decisive role in catalysis, but their synthesis is rather challenging and often involves hazardous chemicals such as PCl3 or PH3. Here, the authors report the one-pot preparation of asymmetric phosp
Externí odkaz:
https://doaj.org/article/fc0054bb3c154684a05404a5a726a097
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-1 (2023)
Externí odkaz:
https://doaj.org/article/9593b287fb8f43fbb32db67726d7d353
Autor:
Prof. Dr. Hans‐Christian Böttcher, Dr. Marion Graf, Dr. Peter Mayer, Prof. Dr. Manfred Scheer
Publikováno v:
ChemistryOpen, Vol 9, Iss 10, Pp 991-995 (2020)
Abstract The synthesis of [Rh2(η5‐Cp)2(μ‐H)(μ‐PPh2)2]BF4 (2) by protonation reaction of the metal basic complex [Rh2(η5‐Cp)2(μ‐PPh2)2] (1) with tetrafluoroboric acid in diethyl ether is described. Complex salt 2 was obtained in high yi
Externí odkaz:
https://doaj.org/article/5064f90f04634907bb526b12cd9dd4a9
Autor:
Thach N. Tu, Manfred Scheer
Publikováno v:
Chem. 9:227-241
Publikováno v:
Chemical Communications. 59:4495-4498
The reaction of pentaphosphaferrocene [Cp*Fe(η5-P5)] with unsaturated cationic transition metal species is investigated as a systematic approach towards the synthesis of multi-decker complexes containing cyclo-P5 ligands.
Autor:
Matthias T. Ackermann, Michael Seidl, Riccardo Grande, Yuqiao Zhou, Michael J. Ferguson, Alexey Y. Timoshkin, Eric Rivard, Manfred Scheer
Publikováno v:
Chemical Science. 14:2313-2317
Reactivity studies on the complex IDipp·GeH2BH2OTf with different pnictogenylboranes were carried out. Hereby, unprecedented cationic group 13/14/15 compounds containing chains of only hydrogen-substituted 13/14/15 elements could be obtained.
Publikováno v:
Chemical Science. 14:3834-3838
A novel synthetic route for (parent) phosphorus-containing cycloalkanes such as phosphetanes, phospholanes, 5 phosphinanes and phosphepanes and their organo-substituted derivatives is reported. For the first time the parent phospholane was synthesise