Proton-assisted activation of a Mn ^III -OOH for aromatic C-H hydroxylation through a putative [Mn ^V O] species.

Autor: Gupta S; Southern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India. appud@iitk.ac.in., Sharma P; Southern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India. appud@iitk.ac.in., Jain K; Southern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India. appud@iitk.ac.in., Chandra B; Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, USA., Mallojjala SC; Department of Chemistry, Binghamton University, Binghamton, New York 13902, USA. sharathc@binghamton.edu., Draksharapu A; Southern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India. appud@iitk.ac.in.

Publikováno v: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jun 20; Vol. 60 (51), pp. 6520-6523. Date of Electronic Publication: 2024 Jun 20.

Altering the Localization of an Unpaired Spin in a Formal Ni(V) Species.

Autor: Awasthi A; Southern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India., Mallojjala SC; Department of Chemistry, Binghamton University, Binghamton, New York, 13902, USA., Kumar R; Southern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India., Eerlapally R; Southern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India., Hirschi JS; Department of Chemistry, Binghamton University, Binghamton, New York, 13902, USA., Draksharapu A; Southern Laboratories-208 A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Jan 16; Vol. 30 (4), pp. e202302824. Date of Electronic Publication: 2023 Nov 27.

Stereospecific Nickel-Catalyzed Cross-Electrophile Coupling Reaction of Alkyl Mesylates and Allylic Difluorides to Access Enantioenriched Vinyl Fluoride-Substituted Cyclopropanes.

Autor: Lin PC; Department of Chemistry, University of California, Irvine, California 92697, United States., Joshi C; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., McGinnis TM; Department of Chemistry, University of California, Irvine, California 92697, United States., Mallojjala SC; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Sanford AB; Department of Chemistry, University of California, Irvine, California 92697, United States., Hirschi JS; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Jarvo ER; Department of Chemistry, University of California, Irvine, California 92697, United States.

Publikováno v: ACS catalysis [ACS Catal] 2023 Mar 20; Vol. 13 (7), pp. 4488-4499. Date of Electronic Publication: 2023 Mar 20 (Print Publication: 2023).

Synthesis of Silicon-Substituted Hemicyanines for Multimodal SWIR Imaging.

Autor: East AK; Department of Chemistry, Beckman Institute for Advanced Science and Technology, and Cancer Center at Illinois, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Lee MC; Department of Chemistry, Beckman Institute for Advanced Science and Technology, and Cancer Center at Illinois, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Smaga LP; Department of Chemistry, Beckman Institute for Advanced Science and Technology, and Cancer Center at Illinois, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Jiang C; Department of Chemistry, Beckman Institute for Advanced Science and Technology, and Cancer Center at Illinois, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Mallojjala SC; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Hirschi JS; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Chan J; Department of Chemistry, Beckman Institute for Advanced Science and Technology, and Cancer Center at Illinois, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States.

Publikováno v: Organic letters [Org Lett] 2022 Nov 25; Vol. 24 (46), pp. 8509-8513. Date of Electronic Publication: 2022 Nov 14.

Probing the Free Energy Landscape of Organophotoredox-Catalyzed Anti-Markovnikov Hydrofunctionalization of Alkenes.

Autor: Mallojjala SC; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Nyagilo VO; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Corio SA; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Adili A; Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States., Dagar A; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Loyer KA; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States., Seidel D; Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States., Hirschi JS; Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2022 Sep 28; Vol. 144 (38), pp. 17692-17699. Date of Electronic Publication: 2022 Sep 16.