Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Malika Ousmer"'
Autor:
Norbert A. Braun, Malika Ousmer, Marco A. Ciufolini, Jonah J. Chang, David Chai, Sylvain Canesi
Publikováno v:
Synthesis. 2007:3759-3772
This contribution reviews a family of reactions devised in our laboratory that effect the oxidative conversion of phenols into 4-amido-dienones. A salient feature of this chemistry is the use of hypervalent iodine reagents, especially diacetoxyiodobe
Publikováno v:
Tetrahedron. 62:5318-5337
We describe the development of a technique for the oxidative conversion of 4-alkyl phenols to derivatives of the corresponding 4-alkyl-4-amino-2,5-cyclohexanediones. This transformation, which was inspired by biogenetic considerations, constitutes a
Publikováno v:
European Journal of Organic Chemistry. 2006:1216-1221
A p-(C-glucopyranosyl)-L-phenylalanine derivative protected to be directly incorporated into a peptidic chain is prepared in 37 % yield from glucose on a gram scale, with a Negishi cross-coupling reaction as the key step. Zincated glucal and p-iodo-L
Publikováno v:
Journal of the American Chemical Society. 123:7534-7538
A solution to the long-standing problem presented by the oxidative cyclization of a phenolic 3-arylpropionamide to a spirolactam has been developed in this laboratory via oxazoline chemistry. This research was motivated by our interest in some novel
Autor:
Norbert A. Braun, Marco A. Ciufolini, Eva-Maria Peters, Jonathan D. Bray, Karl Peters, Denis Bouchu, Malika Ousmer
Publikováno v:
The Journal of Organic Chemistry. 65:4397-4408
The oxidative cyclization of a phenolic amide to a spirolactam has long been regarded as an "impossible" reaction, because exposure of the substrates to a variety of oxidants results in formation of spirolactones with consequent loss of the amine seg
Publikováno v:
European Journal of Organic Chemistry. 1999:3315-3321
Aminocarbene complexes of chromium 1b-d react successively with diphenylacetylene, XH (X = PhS, PhSe, OAc) and finally with pyridine to give a series of functionalized pyrrolinones 7 via N-ylide complexes 2. The X-ray structure of 7b originating from
Publikováno v:
ChemInform. 31
Publikováno v:
ChemInform. 32
Autor:
Sylvain Canesi, Jonah J. Chang, Malika Ousmer, David Chai, Marco A. Ciufolini, Norbert A. Braun
Publikováno v:
ChemInform. 39
This contribution reviews a family of reactions devised in our laboratory that effect the oxidative conversion of phenols into 4-amido-dienones. A salient feature of this chemistry is the use of hypervalent iodine reagents, especially diacetoxyiodobe
Publikováno v:
Organic letters. 3(5)
[structure: see text]. The total synthesis of FR901483, a structurally novel immunosuppressant, has been accomplished by the use of technology recently developed in this laboratory for the oxidative cyclization of phenolic oxazolines to spirolactams.