Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Makoto Ganaha"'
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :2156-2160
Novel yeast reduction which gave (1R,2S)-hydroxy ester 10 and (1S,5S)-lactone 11 from racemic ketoester 12 was discovered. After 10 and 11 were converted to lactone 15 and 17, enantiomeric excesses were determined as 99% and 95%, respectively. This n
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e6dd3397b9aac4aad5954b4b5e91dc22
https://doi.org/10.1039/b206843p
https://doi.org/10.1039/b206843p
Publikováno v:
Bioscience, Biotechnology, and Biochemistry. 62:181-184
Baker's yeast reduction of methyl and ethyl (2-oxocyclohexyl) acetates proceeded with enantio- and diastereo-selectivity, affording the corresponding (2S)-trans-alcohols (major), (2S)-cis-alcohols (minor), and the unaltered (1S)-ketones with high opt
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::82ee3e702f87355e0bd518bd35fb2b37
https://doi.org/10.1271/bbb.62.181
https://doi.org/10.1271/bbb.62.181
Publikováno v:
Bioscience, Biotechnology, and Biochemistry. 63:2025-2027
The synthesis of methyl (S)-(-)-6,8-dihydroxyoctanoate as a precursor of (R)-(+)-α-lipoic acid was accomplished by using methyl (S)-(-)-(2-oxocyclohexyl)acetate, which had been obtained from baker’s yeast reduction, as a chiral starting material.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6ad10cbe57126e843a3bdf900cce7177
https://doi.org/10.1271/bbb.63.2025
https://doi.org/10.1271/bbb.63.2025