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pro vyhledávání: '"Magali Vuagnoux"'
Autor:
Alexandre Alexakis, Magali Vuagnoux-d'Augustin, David Martin, Stefan Kehrli, Laetitia Palais, Hélène Hénon, Christine Hawner
Publikováno v:
CHIMIA, Vol 62, Iss 6 (2008)
This mini-review deals with a special, and challenging, aspect of the asymmetric conjugate addition: the formation of all-carbon quaternary centers by reaction with Michael acceptors bearing a polysubstituted unsaturation. Only copper catalysts allow
Externí odkaz:
https://doaj.org/article/0447e38e95ff47eca0a6351b8f63819f
Publikováno v:
Chemistry – A European Journal. 17:6214-6220
In the search for a new access to thujopsanone related compounds by cycloisomerization reactions of unsaturated propargylic alcohols and acetates, we found several interesting reaction types and demonstrated the complementarity of Au, Pt, and Cu cata
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 17(4)
(E)-Trisubstituted allylic alcohols are commonly prepared from the corresponding (E)-enals, themselves readily accessible by a simple aldol condensation reaction. We demonstrate that these very same (E)-enals can be converted into (Z)-trisubstituted
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 17(14)
Publikováno v:
Angewandte Chemie (International ed. in English). 48(39)
We report herein the first enantioselective, direct synthesis of the highly prized natural sandalwood odorant ( )-b-santalol (( )-1). The key step in the synthesis is an efficient copper-catalyzed rearrangement of an enynol. The increasing scarcity o
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