Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Mads C. Nielsen"'
Publikováno v:
Angewandte Chemie International Edition. 53:5903-5906
To date only three ligands are known to trigger the challenging reductive elimination of ArCF3 from Pd(II). We report the computational design of a bidentate trifluoromethylphosphine ligand that although exhibiting a generally ineffective small bite
Publikováno v:
The Journal of Organic Chemistry. 78:7749-7753
The (trifluoromethyl)stannane reagent, Bu3SnCF3, was found to react under CsF activation with ketones and aldehydes to the corresponding trifluoromethylated stannane ether intermediates at room temperature in high yield. Only a mildly acidic extracti
Publikováno v:
Journal of the American Chemical Society
With the objective to increase understanding of the factors that control selectivities in high oxidation state palladium chemistry we examined the chemoselectivity in the reductive elimination of a dinuclear Pd(III) complex bearing different apical l
Publikováno v:
Helvetica Chimica Acta. 95:2231-2236
(Trifluoromethyl)stannane reagents such as Bu3SnCF3 are effective in CuI-mediated trifluoromethylation reactions of aryl iodides. The reactions proceed via the intermediacy of [CuCF3] species.
Publikováno v:
Angewandte Chemie (International ed. in English). 53(23)
To date only three ligands are known to trigger the challenging reductive elimination of ArCF3 from Pd(II). We report the computational design of a bidentate trifluoromethylphosphine ligand that although exhibiting a generally ineffective small bite
Publikováno v:
ChemInform. 44
Tributyl(trifluoromethyl)stannane is successfully applied for the trifluoromethylation of a variety of carbonyl compounds.
Publikováno v:
The Journal of organic chemistry. 78(15)
The (trifluoromethyl)stannane reagent, Bu3SnCF3, was found to react under CsF activation with ketones and aldehydes to the corresponding trifluoromethylated stannane ether intermediates at room temperature in high yield. Only a mildly acidic extracti
Publikováno v:
ChemInform. 44
(Trifluoromethyl)stannane reagents, such as Bu3SnCF3 (II), are found to be effective trifluoromethylation agents in CuI-mediated transformations of aryl iodides (I).
Publikováno v:
Angewandte Chemie; Aug2006, Vol. 118 Issue 32, p5437-5441, 5p