Impact of the novel Z-acceptor ligand bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the formation and reactivity of low-coordinate Ru(0) centers

Autor: Connie J. Isaac, James C. B. Farmer, Arron L. Burnage, Madeleine L. Beck, Michael K. Whittlesey, Stuart MacGregor, Mary F. Mahon, Fedor M. Miloserdov

Publikováno v: Inorganic Chemistry, 59(21), 15606-15619
Miloserdov, F, Isaac, C, Beck, M, Burnage, A, Farmer, J, Macgregor, S, Mahon, M & Whittlesey, M 2020, ' Impact of the novel Z-acceptor ligand bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the formation and reactivity of low-coordinate Ru(0) centers ', Inorganic Chemistry, vol. 59, no. 21, pp. 15606-15619 . https://doi.org/10.1021/acs.inorgchem.0c01683
Inorganic Chemistry 59 (2020) 21

The preparation and reactivity with H2 of two Ru complexes of the novel ZnPhos ligand (ZnPhos = Zn(o-C6H4PPh2)2) are described. Ru(ZnPhos)(CO)3 (2) and Ru(ZnPhos)(IMe4)2 (4; IMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) are formed directly from the r

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https://research.wur.nl/en/publications/impact-of-the-novel-z-acceptor-ligand-bisortho-diphenylphosphinop