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The Stereochemistry of Organmetallic Compounds. XXV. The Stereochemistry of Displacements of Secondary Methanesulfonate and p-Toluene-sulfonate esters by Diphenylphosphide Ions. X-ray Crystal Structure of (5α- Cholestan- 3α-yl)diphenylphosphine Oxide

Autor: Roy, Jackson W, Thomson, RJ, Mackay.M.F, .

Publikováno v: Australian Journal of Chemistry; 1985, Vol. 38 Issue: 1 p111-118, 8p

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Autor: Jackson W Roy, RJ Thomson, Mackay.M.F

Publikováno v: Australian Journal of Chemistry. 38:111

Reactions of both axial and equatorial cholestan-3α- and -3β-yl mesylates and tosylates with sodium diarylphosphides give cholestanylphosphines in good yield and with complete inversion of stereochemistry. The stereochemistry has been established b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a576c6dbb84983ad75aaac0eea72d639
https://doi.org/10.1071/ch9850111

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