Zobrazeno 1 - 10
of 25
pro vyhledávání: '"M. Yu. Nikiforov"'
Publikováno v:
Russian Journal of Physical Chemistry A. 91:901-904
The effect of concentration on the self-diffusion coefficients of acetylsalicylic acid and methyl salicylate in methanol-d4 is investigated in the temperature range of 278–318 K using NMR. It is found that the self-diffusion coefficients increase a
Publikováno v:
Russian Journal of Physical Chemistry B. 10:1166-1170
Analysis of the experimental data on the solubility of methylxanthines (theophylline and theobromine) in supercritical (SC) solvent CO2–methanol at various concentrations of methanol within the framework of the ASL model (Associated Solution + Latt
Publikováno v:
Russian Journal of Physical Chemistry B. 9:1054-1058
The caffeine–methanol association constant at 313 K has been determined by 1H NMR spectroscopy. The caffeine solubility in the supercritical carbon dioxide (SC-CO2)–methanol mixed solvent has been calculated using the association constant experim
Autor:
M. Yu. Nikiforov, G. A. Al’per, N. Zh. Mamardashvili, Galina M. Mamardashvili, Oscar I. Koifman, Ilya A. Khodov
Publikováno v:
Journal of Molecular Structure. 1081:426-430
Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectr
Autor:
Nikolaj Georgi, S.V. Efimov, G. A. Al’per, M. Yu. Nikiforov, Dmitriy S. Blokhin, Vladimir V. Klochkov, Ilya A. Khodov
Publikováno v:
Journal of Molecular Structure. 1035:358-362
Small organic molecules in dissolved state exist as an ensemble of conformers. In this work conformation of felodipine in dimethyl sulphoxide was studied and dominant stable conformers were determined. Effective interatomic distances were obtained by
Publikováno v:
Journal of Structural Chemistry. 52:304-309
A method based on the statements of molecular association theory and a simple lattice model (ASL = Associated Solution + Lattice) is used to calculate the solubility of a series of porphyrin macrocycles (blood porphyrins) in binary solvents (tetrachl
Publikováno v:
Russian Journal of Physical Chemistry A. 84:950-953
The kinematic viscosity and density of the methanol-n-decane system were measured at various temperatures at low n-decane concentrations (over the miscibility range). The theory of free volume with taking into account molecular association was used t
Publikováno v:
Russian Journal of Physical Chemistry A. 83:45-49
The enthalpies of solution of nonelectrolytes in mixed solvents were calculated using the Associated Solution + Lattice thermodynamic model, whose parameters are equilibrium constants, the enthalpies of formation of associates, and the energy of mutu
Publikováno v:
Journal of Structural Chemistry. 49:1120-1123
Chemical shifts (c.s.) of 1H nuclei in methanol are measured for methanol-benzene and methanol-phenanthrene systems. A method to determine the equilibrium constant of the molecular association reaction by NMR spectroscopy data is proposed for systems
Publikováno v:
Russian Journal of Physical Chemistry. 82:222-227
The kinematic viscosity of n-nonane mixtures with propan-1-ol, butan-1-ol, and pentan-1-ol was measured over the temperature range 293.15–313.15 K. For all systems, negative deviations of viscosity from additive values were obtained; the deviations