Zobrazeno 1 - 10
of 319
pro vyhledávání: '"M. Sluyters-Rehbach"'
Autor:
M. Sluyters-Rehbach, J. H. Sluyters
Publikováno v:
The Journal of Physical Chemistry B. 114:15582-15589
The anomalous behavior of liquid water is apparent from the temperature dependence of many experimental properties. Among these are the abnormal high limiting ionic conductivities λ(0) of protons and hydroxyl ions, which in a previous paper we found
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 82:553-564
The anomalous behaviour of the Tl+/Tl(Hg) electrode in 1 KNO3 + 0.1 M KCl solution has been studied experimentally applying the theory described in parts IV and VI of this series. It is shown that this anomaly can be explained assuming that the doubl
Autor:
J. H. Sluyters, M. Sluyters‐Rehbach
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 83:983-991
A comparison is made of studies of the Hg2++/Hg electrode by means of complex plane analysis 1, 2 and double pulse galvanostatic step 4. As a possible explanation for the inconsistent results, interference by the double layer capacity in the latter m
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 85:303-310
A new and simple derivation of the diffusion polarization as a function of time is presented for the case wherein a square wave current passes an electrode-solution interface. The moment of zero diffusion polarization, which was already known to be 0
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 85:661-670
The sources of error pertaining to the oscilloscopic determination of rate constants of electrode reactions are studied and the upper and lower limits of the methods are given. The former is mainly determined by the accuracy with which the moment of
Autor:
M. Sluyters‐Rehbach, J. H. Sluyters
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 82:525-534
The views developed in parts III and IV of this series are applied to alternating current polarography in the impedance plane. It is shown that from such polarograms a quantity q can be determined which is inversely proportional to concentration. The
Autor:
M. Sluyters‐Rehbach, J. H. Sluyters
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 83:581-586
From impedance measurements it is shown that the hydrogen ion reduction on mercury behaves as a case of pure activation polarization between -1.1 and -1.3 V vs S.C.E. with 1-α = 0.56 and ksh = 10−15 cm · sec−1. The value of the double layer cap
Autor:
J. H. Sluyters, M. Sluyters‐Rehbach
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 83:217-222
The values of the double layer capacity of the mercury-1 M HCIO4 solution interface at potentials where the dissolution of Hg contributes to the cell impedance, have been determined by the method previously described in parts VI1 and VII2.
Autor:
M. Sluyters-Rehbach, J. H. Sluyters
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 82:535-552
The theory developed in part IV1 and part VI2 of this series has been verified by experiments. The results are
Autor:
J. H. Sluyters, M. Sluyters‐Rehbach
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 83:967-975
The accuracy of the double layer capacity measurements at high potentials described in part IX 1 is critically examined, especially with a view to the correct determination of the ohmic resistance of the cell. A limit for the exchange current density