Zobrazeno 1 - 10
of 16
pro vyhledávání: '"M. R. Pressprich"'
Publikováno v:
Journal of Applied Crystallography. 31:128-135
New photocrystallographic and cryogenic techniques are tested in a 40 K study of the 2.44 ms lifetime excited state of [RhBr2(pyridine-d5)]Br. A modulation method is used in which a laser beam is interrupted by a mechanical chopper with a preselected
Publikováno v:
Journal of the American Chemical Society. 119:2669-2678
The geometries of two known metastable states of sodium nitroprusside dihydrate, Na2[Fe(CN)5NO]·2H2O, and that of the ground state have been analyzed by X-ray diffraction at 50 K, a temperature at which no decay of metastable-state concentration wit
Publikováno v:
Journal of Applied Crystallography. 27:727-732
Instrumentation for measuring the X-ray diffraction pattern of optically excited crystals is described. The experiment uses a high-power (~1 W) laser and a single-crystal diffractometer equipped with a helium cryostat (T < 70 K). The laser beam is mo
Publikováno v:
Acta Crystallographica Section A Foundations of Crystallography. 49:216-219
The valence-contrast diffraction method is used at the Nb K edge in the analysis of the mixed-valence solid NbSe3. The NbSe3 structure consists of three parallel chains of prismatically coordinated Nb atoms and undergoes two low-temperature Peierls-t
Autor:
M. R. Pressprich, R. D. Willett
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 47:1188-1191
Cristallisation de (I) dans P2 1 /c avec a=9,859, b=16,762, c=13,716 A, β=90,05°, Z=4; affinement jusqu'a R=0,073. Cristallisation de (II) dans P2 1 /c avec a=9,489, b=15,985, c=13,106 A, β=89,52°, Z=4; affinement jusqu'a R=0,088. Les deux struct
Publikováno v:
Acta Crystallographica Section B Structural Science. 47:337-344
Les composes, isostructuraux, possedent des structures quadratiques inhabituelles, constituees de couches d'anions MCl 4 2− empiles perpendiculairement a l'axe c et alternant avec des couches de cations (CH 3 ) 4 As + . La structure moyenne de cett
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 50:1087-1089
The structure of bis(tetraphenylphosphonium) octa-μ 3 -chloro-hexachlorohexamolybdate(2-) is reported. The structure consists of an [Mo 6 Cl 14 ] 2- cluster anion having a crystallographic center of inversion and two (inversion) symmetry-related tet
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 46:1635-1637
2 C 4 H 5 N 2 O + •Cr 2 O 7 2− cristallise dans P2 1 avec a=8,003, b=6,132, c=14,493 A, β=94,50 o , Z=2; affinement jusqu'a R=0,0602. La structure comprend des anions dichromate discrets 2 fois negatifs lies par des liaisons hydrogene aux cation
Publikováno v:
ChemInform. 21
Publikováno v:
Journal of the American Chemical Society. 114:9214-9215
The tunability of synchrotron radiation makes it possible to vary the scattering power of atoms of specific elements in the vicinity of the atomic absorption edges. The effect is due to the contribution of low-lying electronically excited states to t