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Autor:
J. C. Ameline, Y Delugeard, Eric Anglaret, A Moreac, Karine Chesnel, Jean-Louis Sauvajol, M. Palpacuer, B. Hennion, A. Girard
Publikováno v:
Journal de Chimie Physique et de Physico-Chimie Biologique. 95:1441-1444
Nous presentons un certain nombre de resultats originaux concernant la dynamique vibrationnelle de la phase polymere et des phases obtenues par trempe du CsC 60 . Les spectres infrarouge de la phase polymere sont interpretes dans le cadre d'un abaiss
Publikováno v:
physica status solidi (b). 162:9-60
In the following, in a first part we report and discuss experimental results concerning pristine cis-trans polyacetylene, in a second part we present the different models which have been developed to explain the above preceding results. We have tried
Autor:
Alain Moréac, D. Bormann, A. Girard, J.L. Sauvajol, O. Chauvet, László Forró, F. Brocard, F. Rachdi, M. Palpacuer, Christophe Goze
Publikováno v:
Synthetic Metals. 86:2325-2326
We report a room-temperature Raman investigation of C 60 , stable-in-air phototransformed C 60 and AC 60 phases (A=Rb,Cs) as excited at 776 nm. The existence of a stable-in-air phototransformed C 60 state is confirmed. The low-frequency Raman spectru
Autor:
Joël J. E. Moreau, A.J. Dianoux, M. Palpacuer, J.L. Sauvajol, D. Bormann, Jean-Pierre Lère-Porte
Publikováno v:
Synthetic Metals. 84:569-570
We report the phonon density of states of intrachain and interchain low-frequency modes in polythiophene. These new results were obtained by inelastic incoherent neutron scattering experiments. Raman, photoluminescence and X-ray diffraction spectra m
Publikováno v:
Journal de Physique. 44:1307-1316
This report presents the results of measurements of transmission and reflexion spectra of polyacetylene films in the infrared range 4-25 μm. [CH(I3-) Y]x samples were used with various thickness for iodine doping level Y up to 0.07. We used a high d
Publikováno v:
Le Journal de Physique Colloques. 44:C3-345
The infrared transmission of thin films of polyacetylene has been measured for various doping levels ( 0 ≤ Y ≤ 7%). The analysis of results shows that modes ω1 (1400cm-1) and ω2 (900cm-1) arising from structural defects are stable for Y > 2%, a
Publikováno v:
Synthetic Metals. 28:D197-D201
d.c. and optical conductivity in the far infrared have been measured for iodine doped oriented polyacetylene as a function of temperature and doping level. It is shown that the mechanism limiting the conductivity are not the same for the two processe
Publikováno v:
Polymer. 23:1847-1850
The physical properties of polyacetylene films are strongly modified by doping and in particular its optical absorption drastically increases in the middle infra-red range. The aim of this report is to study the behaviour of infra-red transmission be
Autor:
M Palpacuer, G Mas
Publikováno v:
Nouvelle Revue d'Optique. 7:27-32
Several set-ups using coherent light allow the recording of the autocorrelation function as well as of the power spectral density of speckle patterns observed in the image of a diffuse screen or in the scattering beam itself. Results obtained from th