Zobrazeno 1 - 10
of 11
pro vyhledávání: '"M. N. Ushomirskii"'
Autor:
M. N. Ushomirskii, E. B. Lifshits
Publikováno v:
Theoretical and Experimental Chemistry. 26:286-293
The electronic nature of reaction centers of reactants in the formation of polymethine compounds has been analyzed, and it has been established that the polymethine structures, depending on the combination of parity of the external polymethine chain
Autor:
M. N. Ushomirskii
Publikováno v:
Theoretical and Experimental Chemistry. 26:255-263
On the basis of a principle of stability of heterocyclic compounds and a theory of effective parameters of heterocycles, a method is proposed for the analysis of reactivity of these molecules, through which heterocycles can be selected in a logical m
Autor:
G. G. Dyadyusha, M. N. Ushomirskii
Publikováno v:
Theoretical and Experimental Chemistry. 22:127-134
A method previously proposed for determining the energy structure of a polymethyne dye with any terminal groups is used in considering formulas for the molecularorbital coefficients and the differences in the distribution on the atoms in the polymeth
Publikováno v:
Theoretical and Experimental Chemistry. 21:613-621
The absorption and fluorescence spectra of 6-B-thia- and 6-B-imidathiadimethinemerocyaninocyanines were investigated. It was established that the transition from absorption spectra to fluorescence spectra leads to an underestimation of the deviations
Autor:
G. G. Dyadyusha, M. N. Ushomirskii
Publikováno v:
Theoretical and Experimental Chemistry. 23:10-19
A study has been made on the energy structures and long-wave electronic transitions for linear trinuclear polymethine dyes by the method of additive generating functions. The necessary and sufficient conditions have been established for the occurrenc
Autor:
M. N. Ushomirskii, G. G. Dyadyusha
Publikováno v:
Journal of Structural Chemistry. 28:180-188
A method for solving the secular equation for ..pi..-conjugated molecules with a periodic chain and terminal groups conforming to a definite topology has been proposed. The secular polynomial of the molecule is represented in a trigonometric form, in
Publikováno v:
Journal of Applied Spectroscopy. 40:419-424
Autor:
G. G. Dyadyusha, M. N. Ushomirskii
Publikováno v:
Theoretical and Experimental Chemistry. 21:257-267
A general method has been developed for solving the secular equation of binuclear polymethine dyes, with which the following can be accomplished: Successive approximations can be found in analytical form for all eigenvalues in the spectrum of the top
Publikováno v:
Chemistry of Heterocyclic Compounds. 25:1071-1078
The basicity values of symmetrical polymethine dyes have been compared and correlated with a variety of parameters obtained both experimentally or derived by calculations, as well as with parameters obtained by quantum mechanical methods, characteriz
Autor:
M. N. Ushomirskii, G. G. Dyadyusha
Publikováno v:
Theoretical and Experimental Chemistry. 25:243-247
An additive generative function method previously proposed has been used to derive analytic expressions for the charge and bond-order distributions in polymethine chains for binuclear polymethine compounds. The π-electron wave amplitude is determine