Zobrazeno 1 - 10
of 46
pro vyhledávání: '"M. N. Rudaya"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:1496-1499
β-Polyfluoroalkyl-α,β-enones formed in the E,Z form are converted by the action of atmospheric oxygen into a 93∶7 mixture of E,Z and Z,E isomers in the dark and 60∶40 mixture of these isomers in the light. The Z isomer of 1-phenyl-4,4, 4-trifl
Autor:
Z. E. Skryabina, K. I. Pashkevich, P. N. Kondrat'ev, M. N. Rudaya, T. A. Sinitsyna, Viktor I. Saloutin
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1273-1277
Esters of fluorinated acylpyruvic acids were obtained for the first time. PMR and IR spectroscopy, dipole moment measurements, and quantum chemical calculations showed that these compounds exist as equilibrium mixtures of E and Z enolic isomers.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:1438-1442
1. It has been found that β-ketoesters containing highly fluorinated substituents [CF3, or H(CF2)4] react with ammonia to give β-aminocrotonate esters, or under severe conditions, β-ketoamides. The latter react with a tenfold excess of ammonia to
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1617-1620
1. Polyfluorinated β-ketoesters in the Vilsmeier-Haack reaction form α-formyl-β-chlorovinyl esters. An unsubstituted β-chlorovinyl ester is formed in the case of methyl 4,4-difluoro-3-hydroxybutenoate along with the α-formyl derivative. 2. The r
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:1016-1022
1. The bromination of fluoroalkyl-substituted β-ketoesters using bromine gives unstable α-bromo derivatives which undergo intermolecular rearrangement to yield the starting β-ketoesters and α,α-dibromo-β-ketoesters. 2. An IR spectroscopic and d
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:1653-1655
1. The magnitudes and directions of the dipole moments of fluoroalkyl groups X(CF2)n, where X=F or H, n=1, 2, and 4, have been determined. It has been revealed that there is an increase in the dipole moments of fluoroalkyl groups as the number of F a
Publikováno v:
ChemInform. 19
Publikováno v:
ChemInform. 18
Publikováno v:
Chemischer Informationsdienst. 16
Publikováno v:
ChemInform. 18