Zobrazeno 1 - 10
of 55
pro vyhledávání: '"M. Haddach"'
Publikováno v:
Journal of Labelled Compounds and Radiopharmaceuticals. 42:227-231
A general synthesis of [2-14C]perfluoroalkanes from 1-iodoperfluoroalkanes and ethyl acetate was developed by synthesis of unlabeled perfluorodecane from 1-iodoperfluorooctane. Using the general synthesis, [2-14C]perfluorohexane was synthesized from
Publikováno v:
Tetrahedron. 49:4627-4638
F -alkyl chains perturb the reactivity of substrates in an often unpredictable way. F -alkyl azirine and aziridine carboxylates were prepared from F -alkynylesters, in 80 and 60% yield, respectively, and were found to display reactivities different f
Publikováno v:
Tetrahedron Letters. 34:2469-2472
Strong electrophilic Z and E 3- F -alkyl 2-propenoates have been prepared stereoselectively. Their extremely difficult epoxidation has been achieved with retention of stereohemistry using t-BuO 2 Li, leading to F -alkyl glycidic esters, which are use
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 24
Publikováno v:
ChemInform. 24
Strong electrophilic Z and E 3- F -alkyl 2-propenoates have been prepared stereoselectively. Their extremely difficult epoxidation has been achieved with retention of stereohemistry using t-BuO 2 Li, leading to F -alkyl glycidic esters, which are use
Publikováno v:
Journal of Fluorine Chemistry. 51:197-205
Ethyl-2-F-alcynoates are good substrates for Michael additions. Such additions allowed the preparation of three new families of F-alkylated aminoacids derived from lysine, arginine and cysteine. However, their transformation into betaines has proved
Autor:
D. Drygin, C. Ho, C. Proffitt, M. Haddach, J. Bliesath, M.T.K. Schwaebe, Amy M. Lin, K.L. Anderes, W.A.K. Rice
Publikováno v:
European Journal of Cancer Supplements. 6:108
Publikováno v:
Tetrahedron Letters. 31:1989-1990
The presence of an F-alkyl chain induces particular reactivity and stability in azirinic and aziridinic rings. The newly synthesized F-alkyl azirine carboxylates undergo addition reactions. The F-alkyl aziridine carboxylates are extremely stable towa