Zobrazeno 1 - 10
of 11
pro vyhledávání: '"M. F. Kropman"'
Publikováno v:
Journal of Physics-Condensed Matter, 17(45), S3215-S3224. IOP Publishing Ltd.
We use femtosecond two-colour mid-infrared spectroscopy to study the dynamics of aqueous solutions of salts in HDO:D2O. We find that the lifetime of the O–H stretch vibration of HDO molecules in the solvation shell of the halogenic anions Cl−, Br
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bebed030b2440f23c70487d38f8aa6f8
https://hdl.handle.net/11245/1.246482
https://hdl.handle.net/11245/1.246482
Publikováno v:
Physica Scripta, 69(6), C14-C24. IOP Publishing Ltd.
We study the effects of ions on the structure and dynamics of the hydrogen bonds in liquid water. As a technique we use femtosecond two-color mid-infrared spectroscopy, since this technique allows a clear distinction of the dynamics of the first solv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::409b8eaf3d0a254df77f5ffe64a90c3f
https://hdl.handle.net/11245/1.232464
https://hdl.handle.net/11245/1.232464
Publikováno v:
The Journal of Chemical Physics. 119:12457-12461
The orientational-correlation time of water molecules in ionic solutions has been measured with femtosecond pump–probe spectroscopy. It is found that the addition of ions has no influence on the rotational dynamics of water molecules outside the fi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::48320cde7b9af5ce349fc11b54195d49
https://doi.org/10.1063/1.1623746
https://doi.org/10.1063/1.1623746
Autor:
H. J. Bakker, M. F. Kropman
Publikováno v:
The Journal of Chemical Physics. 115:8942-8948
We use femtosecond two-color mid-infrared spectroscopy to study the dynamics of aqueous solutions of salts in HDO:D2O. We find that the lifetime of the O–H stretch vibration of HDO molecules in the solvation shell of the halogenic anions Cl−, Br
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b123e44a6ba3b44566b1852fd82f6a2d
https://doi.org/10.1063/1.1412249
https://doi.org/10.1063/1.1412249
Publikováno v:
The Journal of Physical Chemistry A. 105:4622-4626
Femtosecond two-color mid-infrared pump−probe spectroscopy is used to study the vibrational relaxation and the hydrogen-bond dynamics of HDO dissolved in liquid H2O. By looking at the spectral dyna...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ba3652604515a2142b4d9516d1c41739
https://doi.org/10.1021/jp010057n
https://doi.org/10.1021/jp010057n
Publikováno v:
Femtochemistry and Femtobiology
Aqueous solvation forms one of the most important but less understood topics of chemical physics. The main problem in the experimental study of aqueous solvation interactions is the distinction of the response of the solvating water molecules from th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bda1963cc377bd5cc099bcb522989faf
https://doi.org/10.1016/b978-044451656-5/50030-x
https://doi.org/10.1016/b978-044451656-5/50030-x
Publikováno v:
Science (New York, N.Y.). 301(5631)
The effects of ions on bulk properties of liquid water, such as viscosity, have suggested that ions alter water's hydrogen-bonding network. We measured the orientational correlation time of water molecules in Mg(ClO 4 ) 2 , NaClO 4 , and Na 2 SO 4 so
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b00a301bbc01b41a063c7820fa1b8ccb
https://pubmed.ncbi.nlm.nih.gov/12869746
https://pubmed.ncbi.nlm.nih.gov/12869746
Publikováno v:
Ultrafast Phenomena XIII ISBN: 9783642639333
Using femtosecond mid-infrared pump-probe spectroscopy, we find that the vibrational energy relaxation, the orientational and hydrogen-bond dynamics of water molecules in the solvation shell of an ion are much slower than in neat liquid water.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::162ec4aa480bf6f7037cf1455c2e3f85
https://doi.org/10.1007/978-3-642-59319-2_133
https://doi.org/10.1007/978-3-642-59319-2_133
Autor:
H. J. Bakker, M. F. Kropman
Publikováno v:
Femtochemistry and Femtobiology.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a6332c10078586ae6f04b1bd7152a75a
https://doi.org/10.1142/9789812777980_0018
https://doi.org/10.1142/9789812777980_0018
Real-Time Measurement of the Orientational Dynamics of Aqueous Solvation Shells in Bulk Liquid Water
Publikováno v:
Physical Review Letters. 88
We present a study of the orientational dynamics of aqueous solvation shells of halogenic anions in bulk water solution with femtosecond two-color midinfrared spectroscopy. These orientational dynamics have time constants between 2.5 and 12 ps, depen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ec7cc2f3c1786f1d0d871f116b67d389
https://doi.org/10.1103/physrevlett.88.077601
https://doi.org/10.1103/physrevlett.88.077601