Zobrazeno 1 - 10
of 15
pro vyhledávání: '"M. E. Brik"'
Publikováno v:
Scopus-Elsevier
Organic-inorganic nanocomposite gels comprising poly(ethyleneoxide) chains grafted between silica particles have been studied by electron paramagnetic and nuclear magnetic resonances. Motional heterogeneity has been investigated as a function of gela
Autor:
M. E. Brik
Publikováno v:
ChemInform. 22
Autor:
M. E. Brik
Publikováno v:
Synthetic Communications. 20:3283-3287
This work reports a new mild reducing agents of 2,2,6,6-tetramethylpiperidine-1-oxyl (1) to hydroxylamine with a good yield. These compounds are: tetrahydroxy-1, 4-quinone (3), 2,5-dihydroxy- 4-benzoquinone (4) and rhodizonic acid (5).
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry Letters. 146:125-133
Using radiolysis of chloroform /CHCl3/, 3,5-dibromo-4-oxo-2,2,6,6-tetramethyl-piperidin-1-oxyl /1/ is oxidized to its corresponding oxoammonium bromide /3/. The mechanism is a one electron oxidation forming the oxoammonium ion /3/ which is stabilized
Autor:
M. E. Brik
Publikováno v:
Synthetic Communications. 20:1487-1495
The reaction of cis 3,5-dibromo-4-oxo-2,2,6,6-tetramethylpiperidin-1-oxyl (1) with polyamines provides a convenient and a short way to synthesize polynitroxides spin labels in a good yield where 3-carboxy-2,2,5,5-tetramethylpyrrolin-1-oxyl (3) is a n
Autor:
M. E. Brik
Publikováno v:
Synthetic Communications. 20:597-601
Selective preparation of cis-3,5-dibromo-4-oxo-2,2,6,6-tetramethylpiperidin-1-hydroxy (6) and in-situ oxidation of alcohols to ketones and aldehydes by oxoammonium bromide in acetic acid as solvent (5) are described.
Publikováno v:
Scopus-Elsevier
The dynamical properties of hybrid materials obtained from mixtures of silicon alkoxides and polyethers are studied. Different techniques are used to analyze the mobility of the different parts of the material: thermal analysis (DSC, DTMA) and NMR to
Autor:
M. E. Brik
Publikováno v:
ChemInform. 21
Autor:
M. E. Brik
Publikováno v:
ChemInform. 21
Publikováno v:
Journal de radiologie. 71(2)
The most important paramagnetic contrast agents used in Nuclear Magnetic Resonance Imaging are limited to a few metal complexes such Gd-DTPA or stable free radicals such as nitroxides simply functionalized. We studied the biodistribution of new polyn