Zobrazeno 1 - 10
of 89
pro vyhledávání: '"M. Dunaj-Jurčo"'
Publikováno v:
Monatshefte fuer Chemie/Chemical Monthly. 132:315-327
The structure of the new compound [Cu(bpy)2N(CN)2]C(CN)3 (6) is compared with thestructures of six copper(II) coordination compounds with phenanthroline or bipyridine ligands and N-donor pseudohalide anions: [Cu(phen)2NCS]C(CN)3 (1), [Cu(bpy)2NCS]C(C
Publikováno v:
Collection of Czechoslovak Chemical Communications. 64:600-612
Crystal structures of Cu(II) compounds with new chelate anionic ligands are presented. The formulae of these compounds are [Cu(bipy)(mcoe)(NCO)] (1) and [Cu(bipy)(coe)] (2), where bipy is 2,2'-bipyridine, mcoe and coe are the anionic chelate ligands
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 54:1760-1763
The crystal structure of [Cu(NCS)(C10H8N2)2][C(CN)3] is composed of discrete [Cu(bipy)2(NCS)]+ cations and [C(CN)3]− anions (bipy is 2,2′-bipyridine). The coordination polyhedron of CuII is a distorted trigonal bipyramid with a {CuN5} chromophore
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 54:33-36
The crystal structure of the title complex, [Cu{ONC-(CN) 2 }(C 12 H 8 N 2 ) 2 (H 2 O)][ONC(CN) 2 ], is composed of discrete [Cu(dcnm)(H 2 O)(phen) 2 ] + cations and dcnm anions [phen is 1,10-phenanthroline and dcnm is dicyanonitrosomethanide, ONC(CN)
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 53:1215-1218
The crystal structure of [Cu{C(CN)3}(C10H8N2)2][C(CN)3] is formed by discrete [Cu(bipy)2{C(CN)3}]+ cations and [C(CN)3]− anions (bipy is 2,2′-bipyridine). The coordination polyhedron of CuII is a distorted trigonal bipyramid with a {CuN5} chromop
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:2406-2409
The crystal structure of the title complex, [Cu(CN)(C 12 H 8 N 2 ) 2 ] 2 (NCS) 2 .C 12 H 8 N 2 .5.5H 2 O, consists of discrete [Cu(CN)(phen) 2 ] + cations (phen is 1,10-phenanthroline), NCS - anions and uncoordinated phen and water molecules. The two
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:2409-2412
A new ligand formation was observed in the title complex, [Cu(C4H4N3O2){N(CN)2}(C10H8N2)], as a result of the nucleophilic addition reaction between methanol and dicyanonitrosomethanide in the inner coordination sphere of a CuII atom. This new ligand
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:532-535
The crystal structure of [Cu(NCS)(C12H8N2)2][C(CN)3] is presented here. The structure comprises discrete [Cu(phen)2(NCS)]+ cations and [C(CN)3]− anions. The coordination polyhedron of CuII is a distorted trigonal bipyramid with a CuN5 chromophore.
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 209:430-436
The result of crystal structure analysis of two Zn–Cu bimetallic complexes are reported. Poly-[diammine-zinc(II)-tricyanocuprate(I)], C3H6N5CuZn, [Zn(NH3)2Cu(CN)3]∞, Mr = 241.03, monoclinic, space group P21/n, a = 6.395(2), b = 6.827(2), c = 17.2
Bis(1,10-phenanthroline)copper(II)-μ-cyano-cyano(1,10-phenanthroline)copper(I) thiocyanate dihydrate
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 50:380-383
By reaction of Cu(NO 3 ) 2 , NH 4 OH, phen (1,10-phenanthroline), KSCN and KCN in the molar ratio 1:40:2:1:1 in a water-ethanol solution a new mixed-valence complex, μ-cyano-1κN:2κC-cyano-2κN-tris(1,10-phenanthroline)-1κ 4 N,N';2k 2 N,N'-dicoppe