Zobrazeno 1 - 10 of 80 pro vyhledávání: '"M. D. RAUSCH"'
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The Utility of Triamminetricarbonylchromium, (NH3)3Cr(CO)3, in the Synthesis of Arenetricarbonylchromium Complexes
Autor: G. A. Moser, M. D. Rausch
Publikováno v: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 4:37-48
Reactions of thiophene, t-butylbenzene, phenyltrimethylsilane and iodobenzene with (NH3)3Cr(CO)3 in refluxing dioxane have produced the corresponding arenetricarbonylchromium complexes in yields as good as or better than similar reactions using Cr(CO
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::83555229848672c82556c5c74da6c69f
https://doi.org/10.1080/00945717408069629
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6
Kinetics and mechanisms of carbonyl substitution reactions of bis(.eta.5-cyclopentadienyl) dicarbonyl compounds of the titanium triad metals
Autor: F. Basolo, G. T. Palmer, M. D. Rausch, L. B. Kool
Publikováno v: Journal of the American Chemical Society. 108:4417-4422
Les nucleophiles pour ces reactions sont PMe 2 Ph, PMePh 2 , PPh 3 , P(OEt) 3 , P(n-Bu) 3 et CO. Les vitesses de reaction sont du 1er ordre avec mecanisme dissociatif. Parametres d'activation
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::31a51fcfabd7a94eef2d3980fb8a4bbf
https://doi.org/10.1021/ja00275a031
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7
The Reaction of (h5-Cyclopentadienyl)carbonyl(triphenylphosphine)iridium and Bis(pentafluorophenyl)acetylene
Autor: R. G. Gastinger, M. D. Rausch
Publikováno v: Zeitschrift für Naturforschung B. 34:700-705
The reaction between (h5-cyclopentadienyl)carbonyl(triphenylphosphine)iridium and bis(pentafluorophenyl)acetylene has been investigated in detail. As in earlier studies involving the analogous cobalt and rhodium complexes, the metallocyclic product 1
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e0bf8e09d997715f824a9dabc4460c57
https://doi.org/10.1515/znb-1979-0511
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9
The Metalation of η6-Benzenetricarbonylchromium1
Autor: W. A. Lee, M. D. Rausch, G. A. Moser
Publikováno v: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 9:357-363
A study of the interaction of η6-benzenetricarbonylchromium (1) and n-butyllithium to form (η6-phenyllithium)tricarbonylchromium (2) under a variety of reaction conditions has been conducted. Using the mixed solvent system of ethyl ether-tetrahydro
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f7822d9781bedbac2a2d6305fd041b1f
https://doi.org/10.1080/00945717908069752
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