Zobrazeno 1 - 10
of 59
pro vyhledávání: '"M. D. Hurley"'
Publikováno v:
Atmospheric Chemistry and Physics, Vol 8, Iss 12, Pp 3141-3147 (2008)
Smog chamber/FTIR techniques were used to study the products and mechanisms of OH radical and Cl atom initiated oxidation of trans-CF3CH=CHF in 700 Torr of N2/O2 diluent at 295±1 K. Hydroxyl radical initiated oxidation leads to the formation of CF3C
Externí odkaz:
https://doaj.org/article/8bd3423521bb47be872d8ec45a3ad383
Publikováno v:
Atmospheric Chemistry and Physics, Vol 7, Iss 22, Pp 5873-5881 (2007)
The formation of formaldehyde via hydrogen atom transfer from the methoxy radical to molecular oxygen is a key step in the atmospheric photochemical oxidation of methane, and in the propagation of deuterium from methane to molecular hydrogen. We repo
Externí odkaz:
https://doaj.org/article/1ad0f2deb37c40b794dc01aa9cd3c558
Publikováno v:
The Journal of Physical Chemistry A. 114:343-354
The products, kinetics, and mechanism of the reaction Cl + 3-pentanone have been measured by UV irradiation of Cl(2)/3-pentanone/N(2) (O(2)) mixtures using primarily GC analysis with selected cross checks by FTIR. In the absence of O(2), the products
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::391dbcc745b2e25e8ff3529a15e3b6aa
https://doi.org/10.1021/jp9083663
https://doi.org/10.1021/jp9083663
Publikováno v:
The Journal of Physical Chemistry A. 113:2424-2437
The products, kinetics, and mechanism of the reaction Cl + butanone have been measured by UV irradiation of Cl(2)/butanone/N(2) (O(2)) mixtures using either GC or FTIR analysis. In the absence of O(2), the products are 1-, 3-, and 4-chlorobutanone wi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d0247ed2e3163f4f99b0beba9f473092
https://doi.org/10.1021/jp809169h
https://doi.org/10.1021/jp809169h
Publikováno v:
The Journal of Physical Chemistry A. 111:1286-1299
The reactions of Cl atoms with cis- and trans-2-butene have been studied using FTIR and GC analyses. The rate constant of the reaction was measured using the relative rate technique. Rate constants for the cis and trans isomers are indistinguishable
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ca4266edb7804446e483fd2a25596ef7
https://doi.org/10.1021/jp067317r
https://doi.org/10.1021/jp067317r
Autor:
Ole John Nielsen, A. Toft, M D Hurley, R C Buck, R L Waterland, Tomoki Nakayama, K. Takahashi, Yutaka Matsumi, M. P. Sulbaek Andersen, Timothy J. Wallington
Publikováno v:
The Journal of Physical Chemistry A. 111:909-915
FTIR-smog chamber techniques were used to study the products of the Cl atom and OH radical initiated oxidation of CF3CH=CH2 in 700 Torr of N2/O2, diluent at 296 K. The Cl atom initiated oxidation of CF3CH=CH2 in 700 Torr of air in the absence of NOx
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::db4798c8994c352db7998083bcd17585
https://doi.org/10.1021/jp066736l
https://doi.org/10.1021/jp066736l
Autor:
H. Chishima, Ole John Nielsen, Timothy J. Wallington, A. Toft, K. Tonokura, Jonathan W. Martin, S. A. Mabury, D. A. Ellis, M. P. Sulbaek Andersen, M D Hurley
Publikováno v:
The Journal of Physical Chemistry A. 110:9854-9860
Smog chamber/Fourier transform infrared (FTIR) techniques were used to measure k(Cl+C(x)F(2x+1)CH(OH)(2)) (x = 1, 3, 4) = (5.84 +/- 0.92) x 10(-13) and k(OH+C(x)F(2x+1)CH(OH)(2)) = (1.22 +/- 0.26) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of N(2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a76304856b1df7d1e06db3189c6dfc3d
https://doi.org/10.1021/jp060404z
https://doi.org/10.1021/jp060404z
Autor:
S. A. Mabury, Akinori Ito, M. D. Hurley, David A. Ellis, Jonathan W. Martin, Donald J. Wuebbles, J. Xia, S. Sillman, M. P. Sulbaek Andersen, Timothy J. Wallington, J. E. Penner, Ole John Nielsen
Publikováno v:
Environmental Science & Technology. 40:924-930
Calculations using a three-dimensional global atmospheric chemistry model (IMPACT) indicate that n-C8F17CH2CH2OH (widely used in industrial and consumer products) degrades in the atmosphere to give perfluorooctanoic acid (PFOA) and other perfluorocar
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bad348c44a2a49a856ef5e973e386e05
https://doi.org/10.1021/es051858x
https://doi.org/10.1021/es051858x
Autor:
T. J. Wallington, Mario J. Molina, M. D. Hurley, N. Taniguchi, Luisa T. Molina, A. G. Guschin
Publikováno v:
The Journal of Physical Chemistry A. 107:2674-2679
Smog-chamber Fourier-transform infrared (FTIR) techniques were used to study the kinetics and photochemistry of C2F5C(O)CF(CF3)2 in 50−700 Torr of air at 296 K. Upper limits for the rate constants ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::64a3f9bdaa8ce4759b6d08cc59e4fcc5
https://doi.org/10.1021/jp0220332
https://doi.org/10.1021/jp0220332
Publikováno v:
The Journal of Physical Chemistry A. 105:5380-5384
FTIR smog chamber techniques were used in the first investigation of the products following oxidation of CH3C⋮N initiated by Cl atom or OH radicals in air at 296 ± 2 K. It is shown that reaction of Cl atoms with CH3C⋮N gives •CH2C⋮N radicals
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::470eb7141d4191de4f753f351f752e58
https://doi.org/10.1021/jp004318p
https://doi.org/10.1021/jp004318p