Zobrazeno 1 - 10
of 30
pro vyhledávání: '"M.‐J. Brekner"'
Publikováno v:
Angewandte Makromolekulare Chemie. 223:121-133
Investigation of the polymerization process and property modification of metallocene-based cycloolefin (COC) shows that this monomer-catalyst combination enables synthesis of a new class of transparent thermoplastic polymers. Metallocene catalysis of
Publikováno v:
Frontiers in Polymer Science ISBN: 9783798506916
Starting with the theoretical considerations of our previous papers [1,3], some practical aspects concerning the shift procedures of rheological data are analysed. The latter can be used for the construction of both isotherm and isochrone master curv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0c4cbbe515e534b782224a92961e9b04
https://doi.org/10.1007/bfb0114030
https://doi.org/10.1007/bfb0114030
Publikováno v:
Die Makromolekulare Chemie. 189:2085-2097
In a previous publication a new concept has been presented for the composition dependence of the glass transition in compatible polymer blends. The concept starts with the idea that besides conformational energy barriers, contacts due to interaction
Publikováno v:
Polymer. 29:78-85
Starting with the idea that, besides conformational energy barriers, surface contacts are responsible for both conformation and ‘free’ volume distribution, a new concept is developed to describe the glass transition in compatible polymer blends.
Autor:
Hans Adam Schneider, M.-J. Brekner
Publikováno v:
Polymer Bulletin. 14:173-178
It is shown that composition dependence of glass-transition in the compatible poly(styrene)-poly(vinylmethylether) blend exhibits deviations from additivity rules derived in the supposition of continuity of the thermodynamic excess functions of mixin
Publikováno v:
Polymer Bulletin. 10:328-335
Starting from EYRING's transition state theory it is demonstrated for systems obeying the superposition principle that the frequency shift factors of isotherm mastercurves of the viscoelastic functions as well as the temperature shift factors of the
Autor:
Claudius Feger, M.-J. Brekner
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 25:2005-2020
Complexes between diphenylcarbamido-dicarboxybenzene and 1-methyl-2-pyrrolidinone, 1/4 and 1/2 M, are obtained by reacting pyromellitic dianhydride with aniline in the solvent 1-methyl-2-pyrrolidinone. Decomplexation and imidization of this diamic ac
Publikováno v:
Polymer Bulletin. 13
Starting from both the three-dimensional diagram of viscoelastic properties in the reciprocal temperature — log frequency — space and the time-temperature interrelation via apparent activation energy of flow, the possibility of theoretical interp
Publikováno v:
Polymer Bulletin. 14
The limitations of the WLF-relation are discussed with respect to their inherent demands concerning universality. The problem of the reference temperature is discussed in some detail, and their constants are related to the temperature T∞ where the
Publikováno v:
Polymer Bulletin. 11
The applicability of an approach is tested experimentally, which interrelates the frequency as well as the temperature shift of isotherm and isochrone viscoelastic data with the apparent activation energy of the viscous flow. The procedure is based o