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Publikováno v:
Canadian Journal of Chemistry. 83:1098-1113
The selective HNO3 nitration of di-n-octylcrown-6 calix[4]arene using different conditions, studied with LCMS and NMR (1H and 13C) spectroscopic techniques, lead to the identification of most of the expected nitro derivative isomeric compounds. The
Publikováno v:
Journal of Agricultural and Food Chemistry. 48:1455-1461
Crocin-a water soluble carotenoid-is found in the fruits of gardenia (Gardenia jasminoides Ellis) and in the stigmas of saffron (Crocus sativus Linne). For crocin purification, gardenia fruits are extracted with 50% acetone, followed by ether washing
Autor:
Simón Hernández-Ortega, L. Torres-Colín, Manuel Jiménez-Estrada, Andre Aumelas, E. Cristobal-Telésforo, C. K. Jankowski, M R Van Calsteren, Ricardo Reyes-Chilpa
Publikováno v:
Scopus-Elsevier
Two novel compounds, celastroidine A (1) and B (2), were isolated from the roots of Hippocratea celastroides K. Their structures were elucidated by spectroscopical and X-ray diffraction studies. Celastroidine A (1) (C50H74O5) was identified as a Diel
Autor:
Raymundo Cruz-Almanza, L.D. Miranda, David Corona, E. Diaz-Torres, A. Fuentes, R. Lopez-Castañares, K. Jankowski, M R Van Calsteren
Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 55:1035-1048
In this paper we report the synthesis and spectral analysis of new heterocyclic derivatives of 4-aryl thieno[3,2-c]pyridines. These functionalized compounds were obtained from heteroaromatic aldehyde derivative and a cyclisation via tandem aza–Witt
Publikováno v:
Natural Product Letters. 12:181-190
The revision of trinervinol (1) structure, a tricyclic diterpene isolated from Piqueria trinervia cav., led to the modification of the double bond position as well as to the inversion of configuration at glycol and possible hydroxymethylene moieties
Publikováno v:
Spectroscopy Letters. 29:87-99
X-ray structure analysis is discussed in order to probe the information about the conformational behaviour of compound 1.
Autor:
Angel Guzman, J. M. Muchowski, M R Van Calsteren, Edvige Galeazzi, J. L. Nava, K. Jankowski, Eduardo Díaz
Publikováno v:
Magnetic Resonance in Chemistry. 33:581-585
The conformation of 1-phenyl-1-(1,2-dimethyl-5-pyrrolyl)-2-(2-methyl-5-benzoyl-1-pyrroly)ethanol, with characteristics of a molecular propeller, is stabilized by intramolecular hydrogen bonding as detected by 1H NMR, NOE difference experiments, 2D NM
Publikováno v:
Magnetic Resonance in Chemistry. 32:321-325
High-field 2D NMR studies were performed on nine neo-clerodane diterpenoids. Unambiguous assignments of the 13 C signals and proton chemical shifts were achieved which led to the revision of some previous assignments
Autor:
William F. Reynolds, C. K. Jankowski, Héctor Barrios, M. R. Van Calsteren, Eduardo Díaz, J. L. Aguilera, Francisco Yuste
Publikováno v:
ChemInform. 24