Výsledky vyhledávání - "M Inés, García"

Transition of trigonal-bipyramidal to square-planar geometries by oxidation of a coordinated tripodal polyphosphine in Pd(ii) and Pt(ii) complexes

Autor: M. Esther García-Fernández, M. Inés García-Seijo, Damián Fernández-Anca

Publikováno v: RSC Adv.. 2:1404-1415

The oxidation reactions of the unusual d8 trigonal-bipyramidal systems [MX(PP3)]X (M = Pd: X = Cl(1), Br(2), I(3); M = Pt: X = Cl(4), Br(5), I(6); PP3 = tris[2-(diphenylphosphino)ethyl]phosphine) by dissociation of the bound phosphino groups with H2O

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d753c1a9c4b5468706be7e05ad5751fc
https://doi.org/10.1039/c1ra00897h

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Influence of the phosphine arrangement on the reactivity of palladium(II) and platinum(II) polyphosphine complexes with copper(I) chloride

Autor: Damián Fernández, Paloma Sevillano, M. Esther García-Fernández, Alfonso Castiñeiras, M. Inés García-Seijo

Publikováno v: Inorganica Chimica Acta. 358:2575-2584

The distorted square-planar complexes [Pd(PNHP)Cl]Cl (1) (PNHP = bis[2-(diphenylphosphino)ethyl]amine), [M(P3)Cl]Cl [P3 = bis[2-(diphenylphosphino)ethyl]phenylphosphine; M = Pd (2), Pt (3)] and [Pt(NP3)Cl]Cl (5) (NP3 = tris[2-(diphenylphosphino)ethyl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::adcf5e237e4e80f0a0063f326bd17b6a
https://doi.org/10.1016/j.ica.2005.03.018

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Synthesis, reactivity and comparative structural studies on copper(I) and gold(I) halo complexes with tripodal polyphosphines in 1:1 metal to ligand ratio. The X-ray crystal structures of three mononuclear neutral compounds

Autor: Damián Fernández-Anca, M. Inés García-Seijo, Robert O. Gould, M. Esther García-Fernández, Paloma Sevillano

Publikováno v: Inorganica Chimica Acta. 353:206-216

Cu(I) and Au(I) halides interact with equimolecular amounts of tripodal polyphosphines as CH3C(CH2PPh2)3(CP3) in CHCl3, N(CH2CH2PPh2)3(NP3) in CH2Cl2 or CH2Cl2–S (S=MeOH, Et2O) and P(CH2CH2PPh2)3 (PP3) in CH2Cl2 to form Cu(CP3)X [X=Br (1), I (2)],

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d293872198c9c97436333ce9ab6d6c15
https://doi.org/10.1016/s0020-1693(03)00253-6

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Five-coordinate aminophosphine platinum(II) complexes containing cysteine derivatives as ligands

Autor: Piedad del Socorro Murdoch, M. Inés García-Seijo, Robert O. Gould, M. Esther García-Fernández, Abraha Habtemariam

Publikováno v: Inorganica Chimica Acta. 335:52-60

The platinum(II) complex, [Pt(NP3)Cl]Cl (1) [NP3=N(CH2CH2PPh2)3] reacts with thiol-containing biomolecules such as N-acetyl- l -cysteine (N-Ac- l -CysH) and the tripeptide reduced glutathione (γ- l -Glu- l -Cys-Gly, GSH) to afford the intensely-colo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::236d6560af281a3af56c70b82dbb45c4
https://doi.org/10.1016/s0020-1693(02)00813-7

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Crystal structure and reactivity of mononuclear cationic palladium(II) and platinum(II) triphos complexes with phenyltin(IV) anions. The formation of polynuclear platinum–triphos ionic and covalent complexes

Autor: M. Inés García-Seijo, M. Esther García-Fernández, Zoltán Berente, László Jánosi, Bernard Mahieu, László Kollár, Alfonso Castiñeiras

Publikováno v: Polyhedron. 20:855-868

The ionic complexes [M(triphos)Cl]X [M = Pd, X = Cl (1), SnCl3 (1a), SnPh2Cl3 (1c); M = Pt, X = Cl (3), SnCl3 (3a), SnPh2Cl3 (3c)], [M(triphos)Cl](2)X [X = SnPh2Cl4, M = Pd (1b), Pt (3b); X = PtCl4, M = Pt (3d)] and [M(triphos)(2)]X-2 [X = SnPh2Cl3,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::21e267e4e75b59e6a73f63ef52a79b43
https://doi.org/10.1016/s0277-5387(01)00716-1

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Influence on reactivity of chloro ligand substitution in mononuclear cationic Pd(II) and Pt(II) triphos complexes: X-ray structure of the nitrate derivatives

Autor: László Kollár, László Jánosi, M. Esther García-Fernández, Damián Fernández, M. Inés García-Seijo, Zoltán Berente, Paloma Sevillano, Alfonso Castiñeiras

Publikováno v: Inorganica Chimica Acta. 312:40-52

The substitution of chloro ligand in [M(triphos)Cl]Cl complexes [M=Pd (1), Pt (2); triphos=Ph2PC2H4P(Ph)C2H4PPh2] by reaction with 1 equiv. of KX resulted in the formation of the ionic complexes [M(triphos)X]Cl [X=I, M=Pd (3), Pt (4); X=CN, M=Pd (5),

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c6023502a56d4690f27c223bcd31b859
https://doi.org/10.1016/s0020-1693(00)00329-7

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Tuneable reactivity with PPh3 and SnX2 of four- and five-coordinate Pd(II) and Pt(II) complexes containing polyphosphines

Autor: M. Inés García-Seijo, Damián Fernández-Anca, M. Esther García-Fernández

Publikováno v: Dalton transactions (Cambridge, England : 2003). 42(28)

The reactivity of the unusual d(8) trigonal-bipyramidal systems [MX(PP3)]X (X = Cl: M = Pd(1a), Pt(2a); X = Br: M = Pd(3a), Pt(4a); X = I: M = Pd(5a), Pt(6a); PP3 = tris[2-(diphenylphosphino)ethyl]phosphine) in CHCl3-CH3OH, the square-pyramidal compo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8476d8ec30f1bf9d52170375284c54b6
https://pubmed.ncbi.nlm.nih.gov/23728361

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A novel strategy for screening-out raw milk contaminated with Mycobacterium bovis on dairy farms by double-tagging PCR and electrochemical genosensing

Autor: Anabel, Lermo, Susana, Liébana, Susana, Campoy, Silvia, Fabiano, M Inés, García, Adriana, Soutullo, Martín J, Zumárraga, Salvador, Alegret, M Isabel, Pividori

Publikováno v: International microbiology : the official journal of the Spanish Society for Microbiology. 13(2)

A highly sensitive assay for rapidly screening-out Mycobacterium bovis in contaminated samples was developed based on electrochemical genosensing. The assay consists of specific amplification and double-tagging of the IS6110 fragment, highly related

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e70bb4f3439866958a1e9d470eb51808
https://pubmed.ncbi.nlm.nih.gov/20890843

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Tripodal polyphosphine ligands as inductors of chelate ring-opening processes in mononuclear palladium(II) and platinum(II) compounds. The X-ray crystal structure of two derivatives containing dangling phosphorus

Autor: Damián Fernández-Anca, M. Esther García-Fernández, M. Inés García-Seijo

Publikováno v: Dalton transactions (Cambridge, England : 2003). 39(9)

The reaction of NP(3) (tris[2-(diphenylphosphino)ethyl]amine and PP(3) (tris[2-(diphenylphosphino)ethyl]phosphine) with the five-coordinate complexes [PdCl(NP(3))]Cl (1) and [MX(PP(3))]X [M = Pd: X = Cl(2), Br(3), I(4); M = Pt: X = Cl(5), Br(6), I(7)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::27c93dfa10ed3a73880633ad2e12f849
https://pubmed.ncbi.nlm.nih.gov/20162206

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Novel chelate ring-opening induced by silver(I) of five-coordinate palladium(II) and platinum(II) complexes containing tripodal polyphosphines

Autor: Alfonso Castiñeiras, Damián Fernández-Anca, M. Inés García-Seijo, M. Esther García-Fernández

Publikováno v: Inorganic chemistry. 47(13)

The ionic complexes [Pd(NP 3)X]X [NP 3 = tris[2-(diphenylphosphino)ethyl]amine, X = Cl (1), Br(2)] and [M(PP 3)X]X [PP 3 = tris[2-(diphenylphosphino)ethyl]phosphine, M = Pd, X = Cl (3), Br(4); M = Pt, X = Cl (5), Br (6)] contain square pyramidal (1,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::16d957b880ccac52f72825b5cbd0bc31
https://pubmed.ncbi.nlm.nih.gov/18507374

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