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Synthesis, characterization, and crystal structures of novel oligomeric Zn(II) and Cd(II) complexes with N,N′-dimethyl-2,2′-biimidazole

Autor: Letitia M Gruia, André L. Beauchamp, Fernande D. Rochon

Publikováno v: Canadian Journal of Chemistry. 85:520-533

Zn(II) and Cd(II) complexes with N,N′-dimethyl-2,2′-biimidazole (Me2biim) were synthesized and characterized by IR spectroscopy and by X-ray crystallographic methods. The reaction of zinc perchlorate with Me2biim produced the dinuclear compound [

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::97032b65ac2719ef34bf7941c3239eb0
https://doi.org/10.1139/v07-061

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Synthesis, characterization and crystal structures of Cd(II) and Zn(II) complexes with 2,2′-biimidazole

Autor: Letitia M. Gruia, Fernande D. Rochon, André L. Beauchamp

Publikováno v: Inorganica Chimica Acta. 360:1825-1840

The reactions of zinc and cadmium salts with 2,2′-biimidazole (H2biim) yielded a series of compounds in which the ligand is coordinated in the chelating bidentate mode. ZnCl2 and [Ag(H2biim)](NO3) in methanol in a 2:1 proportion produced Zn(H2biim)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e558c23bf68a7b72a31388532894ffa1
https://doi.org/10.1016/j.ica.2006.09.029

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Tris(biimidazolato)chromium(III) as a building block for hydrogen-bonded supramolecular assemblies

Autor: Letitia M Gruia, Fernande D. Rochon, André L. Beauchamp

Publikováno v: Canadian Journal of Chemistry. 84:949-959

The trischelate [Cr(H2biim)3](NO3)3 complex of 2,2′-biimidazole (H2biim) was obtained by reacting CrCl3·3THF with [Ag(H2biim)](NO3) in methanol. In the solvent-free material, each ligand forms two N-H···O bonds to a nitrate ion and generates lo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f400f0faeea0ec9689e2fb4d84895128
https://doi.org/10.1139/v06-110

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P22. Immunomodulation induced by resveratrol or genistein on proliferation and apoptosis of tumour colon cells

Autor: M Bostan, C. Hotnog, G Matei, M. Mihaila, L.I. Brasoveanu, M Gruia, D. Hotnog

Publikováno v: Journal for Immunotherapy of Cancer

Colon cancer represents a malignancy with a high incidence and mortality throughout the world, its etiology involving many genetic, immunological and biochemical factors. Anti-cancer drugs might exert their action during physiological pathways of apo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::30d51632e9ee1e4c069d4787d172b4a9
https://doi.org/10.1186/2051-1426-2-s2-p13

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Synthesis and characterization of Pt(II) complexes with amine and carboxylato ligands. Crystal structure of (1,1-cyclobutanedicarboxylato)di(ethylamine)platinum(II)·H2O

Autor: Fernande D. Rochon, Letitia M Gruia

Publikováno v: Inorganica Chimica Acta. 306:193-204

Two methods for the synthesis of compounds of the type cis-PtA2X2 (A2=bidentate amine or two monodentate amines and X2=bidentate or two monodentate carboxylato ligands) were evaluated. The compounds were characterized by multinuclear NMR and IR spect

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::824439cba4d20dbaa62f003c0d05b52e
https://doi.org/10.1016/s0020-1693(00)00171-7

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Detection of foot‐and‐mouth disease by reverse transcription polymerase chain reaction and virus isolation in contact sheep without clinical signs of foot‐and‐mouth disease

Autor: M. Danes, M. Gruia, M Callens, K. De Clercq

Publikováno v: Veterinary Quarterly. 20:37-40

Summary Two non‐vaccinated sheep were experimentally, infected with FMDV and one day later 4 other sheep were brought in contact. Although the contact sheep showed no clinical signs, serology indicated that all sheep became infected. Various secret

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0af7f4ab492ffbdf3882ebfa44ee585a
https://doi.org/10.1080/01652176.1998.9694964

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