Neocortical tissue recovery in severe congenital obstructive hydrocephalus after intraventricular administration of bone marrow-derived mesenchymal stem cells

Autor: María García-Bonilla, Betsaida Ojeda-Pérez, María L. García-Martín, M. Carmen Muñoz-Hernández, Javier Vitorica, Sebastián Jiménez, Manuel Cifuentes, Leonor Santos-Ruíz, Kirill Shumilov, Silvia Claros, Antonia Gutiérrez, Patricia Páez-González, Antonio J. Jiménez

Publikováno v: Stem Cell Research & Therapy, Vol 11, Iss 1, Pp 1-20 (2020)

Abstract Background In obstructive congenital hydrocephalus, cerebrospinal fluid accumulation is associated with high intracranial pressure and the presence of periventricular edema, ischemia/hypoxia, damage of the white matter, and glial reactions i

Externí odkaz: https://doaj.org/article/fbb0e27d4a724efe9eef7178444de300

105 K Wide Room Temperature Spin Transition Memory Due to a Supramolecular Latch Mechanism

Autor: Maksym Seredyuk, Kateryna Znovjyak, Francisco Javier Valverde-Muñoz, Ivan da Silva, M. Carmen Muñoz, Yurii S. Moroz, José Antonio Real

Publikováno v: Journal of the American Chemical Society. 144:14297-14309

Little is known about the mechanisms behind the bistability (memory) of molecular spin transition compounds over broad temperature ranges (100 K). To address this point, we report on a new discrete Fe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5685e94e87ef0fb45b2349a120568310
https://doi.org/10.1021/jacs.2c05417

Spin transition and symmetry-breaking in new mononuclear FeII tren-complexes with up to 38 K hysteresis around room temperature

Autor: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Igor O. Fritsky, José Antonio A Real Cabezos, Vladimir M. Amirkhanov, Kateryna O. Znovjyak, M. Carmen Muñoz

Publikováno v: Inorganic Chemistry Frontiers. 9:537-546

[EN] The structurally simple complex {Fe-II[tren(6F-py)(3)]}(BF4)(2) [tren(6F-py)(3) = tris(3-aza-4-(6-fluoro-2-pyridyl)-3-butenyl)amine] undergoes an abrupt spin transition (ST) with the critical temperature T down arrow(1/2) = 243 K on cooling and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::96664030a59af2d00f3c3dc3859e934b
https://doi.org/10.1039/d1qi00941a

Sublimable complexes with spin switching: chemical design, processing as thin films and integration in graphene-based devices

Autor: Rosa Córdoba, Javier Herrero-Martín, Francisco Javier Valverde Muñoz, Miguel Gavara-Edo, José Antonio Real Cabezos, Eugenio Coronado Miralles, M. Carmen Muñoz

Publikováno v: Gavara-Edo, M.; Valverde-Muñoz, F. J.; Córdoba, R.; Muñoz, M. C.; Herrero-Martín, J.; Real, J. A.; Coronado, E. Sublimable Complexes with Spin Switching: Chemical Design, Processing as Thin Films and Integration in Graphene-Based Devices. Journal of Materials Chemistry C, 2023, 11, 8107-8120. https://doi.org/10.1039/d2tc04120k.

Among the different types of switchable molecular compounds, sublimable Fe(II) SCO molecules provide a suitable platform to develop smart devices that respond to external stimuli. Here we report the synthesis, crystallographic structure and magnetic

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f4ab2185884646d052731c346e430b6
https://hdl.handle.net/10550/87117

Enhanced Interplay between Host–Guest and Spin-Crossover Properties through the Introduction of an N Heteroatom in 2D Hofmann Clathrates

Autor: Carlos Bartual-Murgui, Rubén Turo-Cortés, M. Carmen Muñoz, José Antonio Real, Ivan da Silva, Manuel Meneses-Sánchez

Publikováno v: Inorganic Chemistry. 60:11866-11877

Controlled modulation of the spin-crossover (SCO) behavior through the sorption-desorption of invited molecules is an extensively exploited topic because of its potential applications in molecular sensing. For this purpose, understanding the mechanis

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::be23f9e37d1f8856431802e18fe067bd
https://doi.org/10.1021/acs.inorgchem.1c01925