Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Lynn M. Schurter"'
Publikováno v:
Environmental sciencetechnology. 29(4)
Trichloramine reacts with excess CN- in a stepwise series of Cl + transfer reactions to give CICN and to generate in sequence dichloramine, monochloramine, and ammonia : NCl 3 + CN- + H 2 O→NHCl 2 + ClCN + OH- ; NHCl 2 + CN- + H 2 O→NH 2 Cl + CIC
Publikováno v:
Environmental sciencetechnology. 28(2)
The first step in NH 2 Cl oxidation of NO 2 - is the general acid-assisted formation of nitryl chloride, where k HA is 7.6×10 6 M -2 s -1 for HaO + and is 46 M -2 s -1 for H 2 PO 4 - (25.0 o C, μ=0.50 M). This is the rate-limiting step at very low
Autor:
Simone Aloisio, Lynn M. Schurter, Charles E. Muller, Qian Liu, Dale W. Margerum, Joseph S. Francisco
Publikováno v:
ChemInform. 32
Reactions of ozone with Br-, SO32-, HSO3-, I-, and NO2-, studied by stopped-flow and pulsed-accelerated-flow techniques, are first order in the concentration of O3(aq) and first order in the concentration of each anion. The rate constants increase by
Autor:
Joseph S. Francisco, Lynn M. Schurter, Qian Liu, Simone Aloisio, Charles E. Muller, Dale W. Margerum
Publikováno v:
Inorganic chemistry. 40(17)
Reactions of ozone with Br(-), SO(3)(2-), HSO(3)(-), I(-), and NO(2)(-), studied by stopped-flow and pulsed-accelerated-flow techniques, are first order in the concentration of O(3)(aq) and first order in the concentration of each anion. The rate con