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Autor:
Horst Elias, Andreas Hoernig, Ulrich Koelle, Urban Frey, Helmut Paulus, Jens Stefan Schneider, Andre E. Merbach, Lynda Dadci
Publikováno v:
Inorganic Chemistry. 34:306-315
Publikováno v:
Inorganica Chimica Acta. 206:135-140
The 1 H NMR spectrum of [Rh 2 (e-CH 3 CN) 8 (a-CH 3 CN) 2 ](BF 4 ) 4 supports the presence in solution of this dinuclear species with a 4/1 equatorial/axial ratio. The lability of the axial acetonitrile is high on the NMR time scale, suggesting a dis