Pseudo-Octahedral Iron(II) Complexes with Near-Degenerate Charge Transfer and Ligand Field States at the Franck-Condon Geometry

Autor: Johannes Moll, Robert Naumann, Lukas Sorge, Christoph Förster, Niklas Gessner, Lukas Burkhardt, Naz Ugur, Patrick Nuernberger, Wolfram Seidel, Charusheela Ramanan, Matthias Bauer, Katja Heinze

Publikováno v: Chemistry-A European Journal, 28(57):e202201858, 1-12. Wiley-VCH Verlag
Chemistry – A European Journal
Moll, J, Naumann, R, Sorge, L, Förster, C, Gessner, N, Burkhardt, L, Ugur, N, Nuernberger, P, Seidel, W, Ramanan, C, Bauer, M & Heinze, K 2022, ' Pseudo-Octahedral Iron(II) Complexes with Near-Degenerate Charge Transfer and Ligand Field States at the Franck-Condon Geometry ', Chemistry-A European Journal, vol. 28, no. 57, e202201858, pp. 1-12 . https://doi.org/10.1002/chem.202201858

Increasing the metal-to-ligand charge transfer (MLCT) excited state lifetime of polypyridine iron(II) complexes can be achieved by lowering the ligand's π* orbital energy and by increasing the ligand field splitting. In the homo- and heteroleptic co

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4f4f61437aad87f6a8f7ad9f9a1f386c
http://www.scopus.com/inward/record.url?scp=85135839541&partnerID=8YFLogxK

Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0

Autor: Lukas Burkhardt, Alena M. Sheveleva, Mark R. Ringenberg, Joris van Slageren, Matthias Bauer, Felix Ehrlich, David Hunger, Floriana Tuna, Kim-Isabelle Mehnert, Marc Schnierle, Mario Winkler

Publikováno v: Inorganic Chemistry. 60:2856-2865

Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+ [10/+; dppf = 1,1'-bis(diphenylphosphino)ferrocene] in two oxidation states by an advanced multitechnique experimental approach. A combination of magnetic circular dich

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6d2bc77ecb267d44290488fa79dead72
https://doi.org/10.1021/acs.inorgchem.0c03259

Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy

Autor: Matthias Bauer, Julian Rudolph, Per-Anders Carlsson, Lukas Burkhardt, Michal Nowakowski, Aleksandr Kalinko, Yannik Vukadinovic, Christoph R. Jacob

Publikováno v: Inorganic Chemistry. 59:3551-3561

While the Hieber anion [Fe(CO)3(NO)]− has been reincarnated in the last years as an active catalyst in organic synthesis, there is still a debate about the oxidation state of the central Fe atom an...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::df144ab22bc47e23bc46097f587d511a
https://doi.org/10.1021/acs.inorgchem.9b02092

Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO)

Autor: Mario, Winkler, Marc, Schnierle, Felix, Ehrlich, Kim-Isabelle, Mehnert, David, Hunger, Alena M, Sheveleva, Lukas, Burkhardt, Matthias, Bauer, Floriana, Tuna, Mark R, Ringenberg, Joris, van Slageren

Publikováno v: Inorganic chemistry. 60(5)

Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::7aad983d9134f24fe46297f89571c71b
https://pubmed.ncbi.nlm.nih.gov/33569942

Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad

Autor: Wojciech Gawelda, Lukas Burkhardt, Lennart Schmitz, Ahmet Kertmen, Michal Nowakowski, Marina Huber‐Gedert, Regine Herbst-Irmer, Adam Neuba, Tae-Kyu Choi, Natalia Lindner, Roland Schoch, Jacek Kubicki, Matthias Bauer

Publikováno v: Chemistry-a European journal 27(38), 9905-9918 (2021). doi:10.1002/chem.202100766
Repositorio Institucional del Instituto Madrileño de Estudios Avanzados en Nanociencia
instname
Chemistry (Weinheim an Der Bergstrasse, Germany)
Biblos-e Archivo. Repositorio Institucional de la UAM

Chemistry - a European journal 27(38), 9905 - 9918 (2021). doi:10.1002/chem.202100766
A new base metal iron-cobalt dyad has been obtained by connection between a heteroleptic tetra-NHC iron(II) photosensitizer combining a 2,6-bis[3-(2,6-diisopro

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5a62f5670cc1626f78fb3f0f1af32e8d
https://bib-pubdb1.desy.de/record/474084