Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Luis Jhonatan Bastidas"'
Autor:
E. Lujano, Merlin Rosales, Luis G. Melean, Margarita Borusiak, Francisco Lopez-Linares, Tirza Ascanio, Luis Jhonatan Bastidas, Pablo J. Baricelli
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 278:107-111
The hydrosoluble complex [Rh(μ-Pz)(CO)(TPPMS)] 2 , Pz = pyrazolate ligand, and TPPMS = (C 6 H 5 ) 2 P(C 6 H 4 SO 3 Na) was used as catalytic precursor in the two phase hydrogenation reaction of the individual olefins (1-hexene, styrene, cyclohexene
Publikováno v:
Reaction Kinetics and Catalysis Letters. 92:99-104
The systems prepared in situ by addition of two equivalents of diphosphine [1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp) and 1,4-bis(diphenylphosphino)butane (dppb)] to M2Cl2(COE)4 (M = Rh, Ir; COE = cyclooctene)
Autor:
Merlin Rosales, Luis G. Melean, Luis Jhonatan Bastidas, Pablo J. Baricelli, Margarita Borusiak, Francisco Lopez-Linares, Dayanna Baricelli, E. Lujano
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 271:180-184
The synthesis and characterization of the catalyst precursor HRh(CO)(TPPMS)3 was carried out by ligand exchange techniques starting from HRh(CO)(PPh3)3 with an excess of TPPMS ligand [TPPMS] = (C6H5)2P(m-C6H4SO3Na), or prepared in situ from RhCl3·3H