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pro vyhledávání: '"Luigi Busetto"'
The vinyliminium complexes [Fe2{μ-η1:η3-C(R′){double bond, long}C(R)C{double bond, long}NMe2}(μ-CO)(CO)(Cp)2][SO3CF3] (R = H, R′ = Tol, 6a; R = H, R′ = Me, 6b; R = R′ = Me, 6c; R = H, R′ = CO2Me, 6d; R = R′ = Et, 6e; R = H, R′ = nBu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3d708790b855e4965e16a7da3bdf5f7b
http://hdl.handle.net/11585/190966
http://hdl.handle.net/11585/190966
Publikováno v:
Organometallics. 31:2667-2674
The diiron bridging vinyliminium complexes [Fe2{µ-η1-η3-C=;N(Me)2C(R')=C(R'')}(µ-CO)(CO)(Cp)2][SO3CF3] (R' = H, R''; = SiMe3, 3a; R' = H, R'' = Tol =4-MeC6H4, 3b; R' = Me, R'' = Me, 3c; R' = SPh, R'' = Me, 3d; R' = H, R'' = Fc = [Fe(C5H4)(Cp)], 6
Publikováno v:
Organometallics. 30:1175-1181
The diiron bridging enaminoalkylidene complex [Fe2{μ-η1:η3-C(Fc)CHCH(NMe2)}(μ-CO)(CO)- (Cp)2] (2), containing a ferrocenyl group on the bridging ligand, reacts with HC≡CR, affording the corresponding 3-R-substituted 1,100-biferrocene (R =CPh2OH
Publikováno v:
European Journal of Inorganic Chemistry. 2011:1260-1268
The reactions of vinyliminium complexes [Fe2{μ-η1:η3- C(R)=C(H)C=N(Me)(R)}(μ-CO)(CO)(Cp)2][SO3CF3] (R = Xyl, R = Me, 1a; R = Xyl, R = Tol, 1b; R = Xyl, R = COOMe, 1c; R = Me, R = Me, 1d; R = Me, R = nBu, 1e; R = p-MeOC6H4, R = Me, 1f; Tol = 4-C6H
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 90:1233-1238
Molybdenum sulfide catalysts of varying surface areas were prepared by thermal decomposition of MoS3 at 300, 350, 400, 450 and 500°. The surface areas has been found to be strongly dependent on the rate of heating suggesting a competition between th
Publikováno v:
Organometallics. 28:5382-5394
The synthesis of a novel class of alcohol- and ether-functionalized indenyl ligands, focusing on the haptotropic rearrangements of the hybrid O-indenyl rhenium species, is herein described. η1- Indx OMeRe(CO)5 (12x) and η3-IndxOMeRe(CO)4 (13x, x=a,
Publikováno v:
Organometallics. 28:3465-3472
Reactions of the vinylalkylidene complexes [Fe2{μ- η1:η3-CRCHCH(NMe2)}(μ-CO)(CO)(Cp) 2](R) SiMe3, 1a; Tol, 1b; CO2Me, 1c, Tol) 4-MeC6H4) with HC t CR′ (R′) CPh 2OH, CO2Me, Ph) lead to the formation of a mixture of 1,3-disubstituted ferrocenes
Autor:
Valerio Zanotti, Luigi Busetto
Publikováno v:
Inorganica Chimica Acta. 361:3004-3011
Thiocarbonyl (CS), homologous to the ubiquitous carbonyl ligand, has interesting and unique properties as ligand. Nevertheless it did not reach the widespread use of CO in the formation of transition metal complexes. This short account, dedicated to
Autor:
Luigi Busetto, Fabio Marchetti, Stefano Zacchini, Valerio Zanotti, Marco Dionisio, Mauro Salmi, Rita Mazzoni
Publikováno v:
Journal of Organometallic Chemistry. 693:2383-2391
The zwitterionic vinyliminium complex [Fe2{μ-η1:η3-C(R′) C(S)C N(Me)(Xyl)}(μ-CO)(CO)(Cp)2] (2a) (R′ = p-Me-C6H4 (Tol), Xyl = 2,6-Me2C6H3) undergoes electrophilic addition at the S atom by HSO3CF3, MeSO3CF3, SiMe3Cl, BrCH2Ph, ICH2CH CH2 afford
Publikováno v:
European Journal of Inorganic Chemistry. 2008:2437-2447
The diiron aminocarbyne complexes [Fe 2 {μ-CN(Me)(R)}(μ-CO)(CO)2(Cp) 2 ][S03CF3] (R = Xyl, la; R = 4-C 6 H 4 OMe, 1b; R = Me, 1c; Xyl = 2,6-Me 2 C 6 H 3 ) react with allenes of the type CH 2 =C=CR'R", in the presence of Me 3 NO/Et 3 N, to give the