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pro vyhledávání: '"Lucas Oxtoby"'
The catalytic enantioselective synthesis of α-chiral alkenes and alkynes represents a powerful strategy for rapid generation of molecular complexity. Herein, we report a transient directing group facilitated site-selective palladium-catalyzed reduct
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::619234ffcbcd9586e8f4380b8198860b
https://doi.org/10.26434/chemrxiv-2022-h8w0k
https://doi.org/10.26434/chemrxiv-2022-h8w0k
The site-selective palladium-catalyzed three-component coupling of unactivated alkenyl carbonyl compounds, aryl- or alkenylboronic acids, and N-fluorobenzenesulfonimide is described herein. Tuning of the steric environment on the bidentate directing
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bbb59d7303088b4fffbd7faa8eb3c14b
https://doi.org/10.26434/chemrxiv-2022-t2zb4
https://doi.org/10.26434/chemrxiv-2022-t2zb4
Metal-coordinating directing groups have seen extensive use in the field of transition-metal-mediated functionalization of alkenes; however, their waste-generating installation and removal steps limit the efficiency and practicality of reactions that
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1b535751c0189a810131c708c80b7228
https://doi.org/10.26434/chemrxiv.9795338
https://doi.org/10.26434/chemrxiv.9795338