Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Lucas A. Freeman"'
Autor:
Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster, Robert J. Gilliard
Publikováno v:
Organometallics. 41:3064-3072
Autor:
Kelsie E. Wentz, Andrew Molino, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Robert J. Gilliard
Publikováno v:
Journal of the American Chemical Society. 144:16276-16281
The first structurally characterized example of a trioxaborinanone (
Publikováno v:
Nature Synthesis. 1:439-448
Autor:
Kelsie E. Wentz, Andrew Molino, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Robert J. Gilliard
Publikováno v:
Inorganic chemistry. 61(43)
The impact of the exact spatial arrangement of the alkali metal on the electronic properties of 9-carbene-9-borafluorene monoanions is assessed, and a series of [K][9-CAAC-9-borafluorene] complexes (
Autor:
Asa W. Nichols, Lucas A. Freeman, Haleigh R. Machost, Diane A. Dickie, Robert J. Gilliard, David J. D. Wilson, Andrew Molino, Akachukwu D. Obi, Charles W. Machan
Publikováno v:
Chemical Science. 12:3544-3550
The mono- and dianions of CO2 (i.e., CO2− and CO22−) have been studied for decades as both fundamentally important oxycarbanions (anions containing only C and O atoms) and as critical species in CO2 reduction and fixation chemistry. However, CO2
Autor:
Lucas A, Freeman, Akachukwu D, Obi, Haleigh R, Machost, Andrew, Molino, Asa W, Nichols, Diane A, Dickie, David J D, Wilson, Charles W, Machan, Robert J, Gilliard
Publikováno v:
Chemical Science
The mono- and dianions of CO2 (i.e., CO2− and CO22−) have been studied for decades as both fundamentally important oxycarbanions (anions containing only C and O atoms) and as critical species in CO2 reduction and fixation chemistry. However, CO2
Autor:
Andrew Molino, Kelsie E. Krantz, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Aishvaryadeep Kaur, Robert J. Gilliard, Wenlong Yang
Publikováno v:
Chemistry – A European Journal. 25:12512-12516
The first examples of N-heterocyclic carbene (NHC) and cyclic(alkyl)(amino) carbene (CAAC) stabilized borepinium and borafluorenium heterocycles are reported herein. The optical properties of the heterocyclic borenium cations were tuned by varying th
Autor:
Lucas A. Freeman, Robert J. Gilliard, Akachukwu D. Obi, Andrew Molino, David J. D. Wilson, Jacob E. Walley, Diane A. Dickie, Guo-Cang Wang
Publikováno v:
Inorganic Chemistry. 58:10554-10568
In the past two decades, the organometallic chemistry of the alkaline earth elements has experienced a renaissance due in part to developments in ligand stabilization strategies. In order to expand the scope of redox chemistry known for magnesium and
Autor:
Diane A. Dickie, Lucas A. Freeman, Lauren E. Lieske, Guo-Cang Wang, Charles W. Machan, Robert J. Gilliard
Publikováno v:
Chemistry – A European Journal. 25:6098-6101
Carbenes are known to activate carbon dioxide to form zwitterionic adducts. Their inherent metal-free redox activity remains understudied. Herein, we demonstrate that zwitterionic adducts of carbon dioxide formed with cyclic(alkyl)(amino) carbenes ar
Autor:
Lucas A. Freeman, Guo-Cang Wang, Zoltán Benkő, Diane A. Dickie, Réka Mokrai, Robert J. Gilliard
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The long‐sought carbene–bismuthinidene, (CAAC)Bi(Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐tox