Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Lucas A. Freeman"'
Publikováno v:
Catalysts, Vol 9, Iss 11, p 934 (2019)
Recently, we have witnessed significant progress with regard to the synthesis of molecular alkaline earth metal reagents and catalysts. To provide new precursors for light alkaline earth metal chemistry, molecular aryloxide and alkoxide complexes of
Externí odkaz:
https://doaj.org/article/7cf69bddee4f4205bfc30feac8fcba20
Autor:
Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster, Robert J. Gilliard
Publikováno v:
Organometallics. 41:3064-3072
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::df7553db0e1400e3d3882d493f97b42e
https://doi.org/10.1021/acs.organomet.2c00464
https://doi.org/10.1021/acs.organomet.2c00464
Autor:
Kelsie E. Wentz, Andrew Molino, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Robert J. Gilliard
Publikováno v:
Journal of the American Chemical Society. 144:16276-16281
The first structurally characterized example of a trioxaborinanone (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e87d1200311c18fdda17acebae9f2578
https://doi.org/10.1021/jacs.2c06845
https://doi.org/10.1021/jacs.2c06845
Publikováno v:
Nature Synthesis. 1:439-448
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::424282239076637baf6abad60b497bbc
https://doi.org/10.1038/s44160-022-00077-6
https://doi.org/10.1038/s44160-022-00077-6
Autor:
Kelsie E. Wentz, Andrew Molino, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Robert J. Gilliard
Publikováno v:
Inorganic chemistry. 61(43)
The impact of the exact spatial arrangement of the alkali metal on the electronic properties of 9-carbene-9-borafluorene monoanions is assessed, and a series of [K][9-CAAC-9-borafluorene] complexes (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e2855c7f4a01bd96c07ce026a363af9
https://pubmed.ncbi.nlm.nih.gov/36259945
https://pubmed.ncbi.nlm.nih.gov/36259945
Autor:
Asa W. Nichols, Lucas A. Freeman, Haleigh R. Machost, Diane A. Dickie, Robert J. Gilliard, David J. D. Wilson, Andrew Molino, Akachukwu D. Obi, Charles W. Machan
Publikováno v:
Chemical Science. 12:3544-3550
The mono- and dianions of CO2 (i.e., CO2− and CO22−) have been studied for decades as both fundamentally important oxycarbanions (anions containing only C and O atoms) and as critical species in CO2 reduction and fixation chemistry. However, CO2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::59fe4c38c0ab2950d2ba1210a09f4741
https://doi.org/10.1039/d0sc06851a
https://doi.org/10.1039/d0sc06851a
Autor:
Lucas A, Freeman, Akachukwu D, Obi, Haleigh R, Machost, Andrew, Molino, Asa W, Nichols, Diane A, Dickie, David J D, Wilson, Charles W, Machan, Robert J, Gilliard
Publikováno v:
Chemical Science
The mono- and dianions of CO2 (i.e., CO2− and CO22−) have been studied for decades as both fundamentally important oxycarbanions (anions containing only C and O atoms) and as critical species in CO2 reduction and fixation chemistry. However, CO2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::63bc6c2ab9c1c7603205d15e82ac91de
https://pubmed.ncbi.nlm.nih.gov/34163627
https://pubmed.ncbi.nlm.nih.gov/34163627
Autor:
Andrew Molino, Kelsie E. Krantz, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Aishvaryadeep Kaur, Robert J. Gilliard, Wenlong Yang
Publikováno v:
Chemistry – A European Journal. 25:12512-12516
The first examples of N-heterocyclic carbene (NHC) and cyclic(alkyl)(amino) carbene (CAAC) stabilized borepinium and borafluorenium heterocycles are reported herein. The optical properties of the heterocyclic borenium cations were tuned by varying th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0ff880038b8606bd68a7fc4932da8356
https://doi.org/10.1002/chem.201903348
https://doi.org/10.1002/chem.201903348
Autor:
Lucas A. Freeman, Robert J. Gilliard, Akachukwu D. Obi, Andrew Molino, David J. D. Wilson, Jacob E. Walley, Diane A. Dickie, Guo-Cang Wang
Publikováno v:
Inorganic Chemistry. 58:10554-10568
In the past two decades, the organometallic chemistry of the alkaline earth elements has experienced a renaissance due in part to developments in ligand stabilization strategies. In order to expand the scope of redox chemistry known for magnesium and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0a94022e986e4e9a25d9572bd3ef254f
https://doi.org/10.1021/acs.inorgchem.9b01058
https://doi.org/10.1021/acs.inorgchem.9b01058
Autor:
Diane A. Dickie, Lucas A. Freeman, Lauren E. Lieske, Guo-Cang Wang, Charles W. Machan, Robert J. Gilliard
Publikováno v:
Chemistry – A European Journal. 25:6098-6101
Carbenes are known to activate carbon dioxide to form zwitterionic adducts. Their inherent metal-free redox activity remains understudied. Herein, we demonstrate that zwitterionic adducts of carbon dioxide formed with cyclic(alkyl)(amino) carbenes ar
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::606b71e3c774cab022da34a6ea273275
https://doi.org/10.1002/chem.201900316
https://doi.org/10.1002/chem.201900316