Influence of the Nucleophilic Ligand on the Reactivity of Carbonyl Rhenium(I) Complexes towards Methyl Propiolate: A Computational Chemistry Perspective

Autor: Daniel Álvarez, Elena López-Castro, Arturo Guerrero, Lucía Riera, Julio Pérez, Jesús Díaz, M. Isabel Menéndez, Ramón López

Publikováno v: Molecules, Vol 25, Iss 18, p 4134 (2020)

A comparative theoretical study on the reactivity of the complexes [ReY(CO)3(bipy)] (Y = NH2, NHMe, NHpTol, OH, OMe, OPh, PH2, PHMe, PMe2, PHPh, PPh2, PMePh, SH, SMe, SPh; bipy = 2,2′-bipyridine) towards methyl propiolate was carried out to analyze

Externí odkaz: https://doaj.org/article/58be5d4ece7246bca02cf0a8ba7a5f12

Strongly Electron-Donating Triazolylidene Ligands: Cationic Metal Carbonyl Complexes of 1-Methyl-1,2,3-triazole as Triazolium Surrogates

Autor: Purificación Cañadas, Jesús Díaz, Julio Pérez, Lucía Riera

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname

A new strategy for tuning the electronic properties of 1,2,3-triazol-5-ylidene metal complexes is reported using {Mo(η3-C4H7)(bipy)(CO)2} or {Re(bipy)(CO)3} fragments as substituents at the triazole N3 atom. The reaction of cationic molybdenum(II) a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::184b4b913dfa960c04a9602ae4755abc
https://pubmed.ncbi.nlm.nih.gov/34990546

Building C(sp3) molecular complexity on 2,2′‐bipyridine and 1,10‐phenanthroline in rhenium tricarbonyl complexes

Autor: Rebeca Arevalo, Larry R. Falvello, Lucía Riera, Julio Pérez, Ramón López

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Zaguán. Repositorio Digital de la Universidad de Zaragoza
Consejo Superior de Investigaciones Científicas (CSIC)
Scopus
RUO. Repositorio Institucional de la Universidad de Oviedo
Universidad de las Islas Baleares

The reactions of [Re(N‐N)(CO)3(PMe3)]OTf (N‐N=2,2′‐bipyridine, bipy; 1,10‐phenanthroline, phen) compounds with tBuLi and with LiHBEt3 have been explored. Addition to the N‐N chelate took place with different site‐selectivity depending o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0b575e9147028baa57c84ae978513399
http://hdl.handle.net/10261/234539

Influence of the nucleophilic ligand on the reactivity of carbonyl rhenium(I) complexes towards methyl propiolate: a computational chemistry perspective

Autor: Ramón López, Elena López-Castro, M. Isabel Menéndez, Daniel Álvarez, Arturo Guerrero, Lucía Riera, Julio Pérez, Jesús Díaz

Publikováno v: Scopus
Molecules
Digital.CSIC. Repositorio Institucional del CSIC
instname
Molecules, Vol 25, Iss 4134, p 4134 (2020)
Volume 25
Issue 18
RUO. Repositorio Institucional de la Universidad de Oviedo

This article belongs to the Special Issue Theoretical Inorganic Chemistry.
A comparative theoretical study on the reactivity of the complexes [ReY(CO)3(bipy)] (Y = NH2, NHMe, NHpTol, OH, OMe, OPh, PH2, PHMe, PMe2, PHPh, PPh2, PMePh, SH, SMe, SPh

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cb33fed8f6dd6d868e967516304aff7
http://hdl.handle.net/10651/58327

Intermolecular C-C Coupling between 1-Methyl-1,2,3-Triazole and 2,2'-Bipyridine or 1,10-Phenanthroline in Mo

Autor: Sergio, Fombona, Julio, Pérez, Jesús, Díaz, Lucía, Riera

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 23(71)

Unsupported 1-methyl-1,2,3-triazole has been coordinated to {Mo(η

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::04f462eee4a1f16b86c826d1834c2c0b
https://pubmed.ncbi.nlm.nih.gov/28910507