Výsledky vyhledávání - "Lourdes Ibarlucea"

(Diphenylphosphino)alkylaldehyde affords hydride- or alkyl-[(diphenylphosphino)alkylacyl]rhodium(iii) or (diphenylphosphino)alkylester complexes: theoretical and experimental diastereoselectivity

Autor: Susan Azpeitia, María A. Garralda, Lourdes Ibarlucea, José M. Seco, Miguel A. Huertos, Montserrat Barquín, Claudio Mendicute-Fierro, Antonio Rodríguez-Diéguez, Eider San Sebastian

Publikováno v: Dalton Transactions. 48:3300-3313

The reaction of [RhCl(COD)]2 (COD = 1,5-cyclooctadiene) with racemic PPh2(CH(Ph)CH2CHO) and pyridine (py) led to the oxidative addition of the aldehyde, and a single geometric isomer of [RhHCl(PPh2(CH(Ph)CH2CO))(py)2] (1), with hydride trans to chlor

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4b90d90d2fd070c04d31ee2fb571eb74
https://doi.org/10.1039/c8dt04929g

Zobrazit plný text záznamu

A pentacoordinated norbornenyl-acyl-rhodium(iii) complex as a likely intermediate in the catalytic hydroacylation of norbornadiene

Autor: María A. Garralda, José M. Seco, Antonio Rodríguez-Diéguez, Claudio Mendicute-Fierro, Lourdes Ibarlucea, Miguel A. Huertos, N. Almenara

Publikováno v: Dalton Transactions. 45:18502-18509

[RhCl(NCO)(nbyl)(PR3)] (nbyl = σ-norbornenyl; NCO = quinoline-8-acyl; R = p-F-C6H4) (1) has been synthesized by the reaction of [Rh(nbd)Cl]2 (nbd = norbornadiene) with 2 equivalents of NCHO (quinoline-8-carbaldehyde) and 2 equivalents of PR3. Compou

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8fbb3c4c05351688b5df40e5c4056087
https://doi.org/10.1039/c6dt03778j

Zobrazit plný text záznamu

Secondary Oxide Phosphines to Promote Tandem Acyl-Alkyl Coupling/Hydrogen Transfer to Afford (Hydroxyalkyl)rhodium Complexes. Theoretical and Experimental Studies

Autor: Antonio Rodríguez-Diéguez, José M. Seco, Virginia San Nacianceno, Antonio J. Mota, Lourdes Ibarlucea, Claudio Mendicute-Fierro, María A. Garralda

Publikováno v: Inorganic chemistry. 57(9)

Acyl(σ-norbornenyl)rhodium(III) dimer [Rh(μ-Cl)(C9H6NCO)(C7H9)L]2 (1) (C7H9 = σ-norbornenyl; L = 4-picoline, isoquinoline) reacts with diphenylphosphine oxide (SPO) to undergo a one-pot reaction in...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f900d2fc2990f9b88693a98b2835960d
https://pubmed.ncbi.nlm.nih.gov/29659263

Zobrazit plný text záznamu

Hydrido{(acylphosphine)(diphenylphosphinous acid)}rhodium(III) Complexes. Catalysts for the Homogeneous Hydrolysis of Ammonia- or Amine-Boranes under Air

Autor: José M. Seco, Itziar Zumeta, Claudio Mendicute-Fierro, Virginia San Nacianceno, Carlos Ubide, Lourdes Ibarlucea, María A. Garralda, Antonio Rodríguez-Diéguez

Publikováno v: Organometallics. 33:6044-6052

The reaction of [RhCl(COD)]2 (COD = 1,5-cyclooctadiene) with PPh2(o-C6H4CHO) (Rh/P = 1:1) in the presence of 4-methylpyridine (4-pic) or isoquinoline (iquin) leads to hydridoacyl complexes [RhHCl(PPh2(o-C6H4CO))L2] (L = 4-pic, 1; iquin, 2). Their rea

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::01e81294d63691adce78e679f4e7fac4
https://doi.org/10.1021/om500666w

Zobrazit plný text záznamu

Reactivity of Quinoline-8-carbaldehyde toward Platina-β-diketone and Acetyl(amine)platinum(II) Complexes. Formation of Acyl(hydroxyalkyl)platinum(IV)

Autor: Lourdes Ibarlucea, Itziar Zumeta, Tim Kluge, Dirk Steinborn, Claudio Mendicute-Fierro, Cristoph Wagner, Tobias Rüffer, Virginia San Nacianceno, María A. Garralda

Publikováno v: Organometallics. 33:788-795

The reaction of the platina-β-diketone [Pt2{(COMe)2H}2(μ-Cl)2] (1) with quinoline-8-carbaldehyde (C9H6NCHO) in MeOH/H2O (Pt/C9H6NCHO = 1/2) leads to the cleavage of the chloride bridges in 1 with acetaldehyde displacement and to the formation of th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fc16a8292f452092d0f19088b92fb5e5
https://doi.org/10.1021/om4011774

Zobrazit plný text záznamu

Iridium and Rhodium Complexes with the Hemilabile Ligand [2‐(1,3‐Dioxolane‐2‐yl)phenyl]diphenylphosphane – Behaviour in Solution and Structural Characterization

Autor: Antonio Rodríguez-Diéguez, José M. Seco, Roberto Ciganda, Montserrat Barquín, Lourdes Ibarlucea, María A. Garralda, Claudio Mendicute-Fierro

Publikováno v: European Journal of Inorganic Chemistry. 2013:1225-1235

[MCl(L2)]2 (M = Ir, L2 = 1,5-cyclooctadiene; M = Rh, L2 = norbornadiene) reacts with [2-(1,3-dioxolane-2-yl)phenyl]diphenylphosphane (1) to afford [MCl(L2)(P~O)] (M = Ir, 2; M = Rh, 3), in which the ligand is P-monodentate. Complex 3 reacts with AgCl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4452561fa470c5f49f30fda39f17ffbf
https://doi.org/10.1002/ejic.201201188

Zobrazit plný text záznamu

New Acylhydrido‐ and Diacylrhodium(III) Organocomplexes Derived from 8‐Quinolinecarbaldehyde and/or o ‐(Diphenylphosphanyl)benzaldehyde

Autor: M. Carmen Torralba, Virginia San Nacianceno, Ricardo Hernández, Lourdes Ibarlucea, Itziar Zumeta, M. Rosario Torres, Claudio Mendicute-Fierro, María A. Garralda, Montserrat Barquín

Publikováno v: European Journal of Inorganic Chemistry. 2012:1445-1452

The acylhydridorhodium(III) complex [RhHCl{PPh2(o-C6H4CO)}(py)2] (1) reacts with 8-quinolinecarbaldehyde (C9H6NCHO) to afford mixed diacyl [RhCl(C9H6NCO){PPh2(o-C6H4CO)}(py)] (2) with acyl groups trans to chlorine and to pyridine. Complex 1 undergoes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e81d7225a3fa847cafdb5f368fbf9851
https://doi.org/10.1002/ejic.201100904

Zobrazit plný text záznamu

Dehydrogenation of Hydridoirida‐β‐diketones in Methanol: The Selective Formation of Mono‐ and Dinuclear Acyl Complexes

Autor: M. Rosario Torres, Elena Pinilla, Roberto Ciganda, María A. Garralda, Claudio Mendicute, Lourdes Ibarlucea

Publikováno v: European Journal of Inorganic Chemistry. 2010:3167-3173

The hydridoirida-β-diketone [IrH{(PPh 2 (o-C 6 H 4 CO)) 2 H}CI] (1) reacts with diimines (NN) or with pyridine (py) in refluxing methanol to undergo dehydrogenation. The reactions afford selectively the cis-acyl, trans-phosphane isomers of the catio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6e4bfd45e73c1aed123e58372b3b0491
https://doi.org/10.1002/ejic.201000250

Zobrazit plný text záznamu

Selective Formation of Rhodium Diacyl or Acyl Hydrido Hemiaminal Complexes in the Reaction of o-(Diphenylphosphino)benzaldehyde with Rhodium 2-Aminopyridine or 2-(Aminomethyl)pyridine Compounds

Autor: Elena Pinilla, Ricardo Hernández, Lourdes Ibarlucea, and M. Rosario Torres, Malkoa Zarandona, María A. Garralda

Publikováno v: Organometallics. 26:5369-5376

[RhCl(COD)]2 (COD = 1,5-cyclooctadiene) reacts with PPh2(o-C6H4CHO) in the presence of 2-aminopyridine (apy) to give the diacyl [RhCl(PPh2(o-C6H4CO))2(apy)] (1) with evolution of hydrogen. 1 is a mixture of two isomers, 1a with trans P atoms and cis

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5e2af683478cfa66b6d2885ac829b67e
https://doi.org/10.1021/om7005134

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání