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pro vyhledávání: '"Louis Carlson"'
Publikováno v:
Organometallics. 31:1653-1663
A novel method for the low-temperature generation of Co2(CO)6-complexed propargyl radicals is developed. It consists of an in situ preparation of the respective cationic species (−50 to −10 °C) and their rapid reduction with cobaltocene, Cp2Co,
Autor:
Arthur Floruti, and Norman Dean, Louis Carlson, Gagik G. Melikyan, Pogban Toure, Lucin Devletyan
Publikováno v:
Organometallics. 26:3173-3182
Chemo- and diastereoselectivities of homo- and cross-coupling reactions of Co2(CO)6-complexed propargyl radicals were studied. The alternative radical generation methodsreduction of respective cati...
Publikováno v:
Dalton Transactions. 42:14801
Applicability of the term "free radical" to organometallic radicals was studied by using the stereoselectivity of radical C-C bond formation as a diagnostic tool. Based on diastereoselectivity data, it was concluded that the reduction of π-bonded, C
Publikováno v:
Organometallics; Jun2007, Vol. 26 Issue 13, p3173-3182, 10p