Zobrazeno 1 - 10
of 35
pro vyhledávání: '"Louis Y. Kuo"'
Autor:
Pierre Moënne-Loccoz, Jordan A. M. Gonzalez, Cayden X. Bullock, Ellie A. Draves, Louis Y. Kuo, Cooper S. Jamieson, Buck L. H. Taylor
Publikováno v:
Inorganic Chemistry. 60:7762-7772
Sulfide oxidation is accomplished by a new class of dioxomolybdenum(VI) catalyst (1) that uses the tridentate 2,6-bis[hydroxyl(methyl)amino]-4-morpholino-1,3,5-triazine ligand to form a five-coordinate molybdenum(VI) center. Resonance Raman spectra s
Autor:
Louis Y. Kuo, Megan Ng, Lauren Kang, Kei Inoue, Joe Seaman, Owen Phillips, Emily K. Bright, Qianli Miao
Publikováno v:
Inorganica Chimica Acta. 483:229-234
A polystyrene-supported molybdate-peroxide polymer (Mo-Y(s)) destroys phosphorothioate pesticides of the form (ArO)P(=S)(OEt)2 in EtOH under mild oxidative (H2O2) conditions and produces a commodity organophosphate. This is the first report of a meta
Publikováno v:
Inorganica Chimica Acta. 466:1-7
A novel protocol for hydrolyzing phosphonothioate neurotoxins has been developed that uses a readily available, inexpensive and non-toxic molybdate (MoO 4 2− ). The target organophosphate is O,S -diethylphenyl phosphonothioate ( 1 ), a model compou
Publikováno v:
Inorganic Chemistry. 56:10013-10020
A polystyrene-supported molybdenum peroxo material [Mo-Y(s)] was applied toward the oxidative degradation of the organophosphate neurotoxin O,S-diethylphenyl phosphonothioate (1) through ethanolysis. In addition to the operational advantages of the h
Publikováno v:
Bioorganic & Medicinal Chemistry. 25:3053-3058
The inhibition kinetics and stereospecificity of the chiral nerve agent derivative O , S -diethylphenylphosphonothioate (DEPP) were examined for two forms of acetylcholinesterase (human and eel) and equine butyrylcholinesterase. Both S- and R-DEPP ar
Autor:
Frances E. Delaney, Louis Y. Kuo
Publikováno v:
Inorganica Chimica Acta. 435:335-339
The water-soluble coordination compound hexaaquaruthenium(II) p-toluene sulfonate (1) catalyzes olefin isomerization that makes it a useful catalyst in unmasking allyl ether and ester protecting groups in water. Allyl ethers of alcohols and acetic ac
Publikováno v:
Organometallics. 32:4759-4765
The metallocene bis(cyclopentadienyl)molybdenum(IV) dichloride Cp2MoCl2 hydrolyzes O,S-diethyl phenylphosphonothioate (1) with only P–S scission to yield a phosphonate under mild aqueous conditions. In terms of degrading phosphonothioate neurotoxin
Publikováno v:
Organometallics. 32:2902-2907
The aqueous chemistry of the air-stable Mo(V) metallocene [Cp2MoCl2]BF4 (1) yields an unexpected autocatalytic reduction when water is added to an acetonitrile solution of 1. While 1 yields the exp...
Publikováno v:
Organometallics. 31:5294-5301
The metallocene bis(cyclopentadienyl)molybdenum(IV) dichloride (Cp2MoCl2; Cp = η5-C5H5) is the first organometallic compound to promote the hydrolysis of phosphonothioates with selective P–S scission in a stoichiometric fashion. This report shows
Publikováno v:
Organometallics. 27:2560-2564
We report the first case of a metal complex that degrades a neurotoxin mimic under extremely mild conditions (pH 6.8, room temperature). The metallocene bis(η5-cyclopentadienyl)molybdenum(IV) dichl...