Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Lorna M. Doyle"'
Autor:
Chakadola Panda, Onyinyechukwuka Anny-Nzekwue, Lorna M. Doyle, Robert Gericke, Aidan R. McDonald
Publikováno v:
JACS Au. 3:919-928
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::26e8b44c440618c8efbded7a918dfa63
https://doi.org/10.1021/jacsau.3c00021
https://doi.org/10.1021/jacsau.3c00021
Publikováno v:
Inorganic Chemistry
Metal-halides that perform proton coupled electron-transfer (PCET) oxidation are an important new class of high-valent oxidant. In investigating metal-dihalides, we reacted [FeIII(Cl)(T(OMe)PP)] (1...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::66f74b3ef15550ccdf27d8b54956286e
https://doi.org/10.1021/acs.inorgchem.0c01618
https://doi.org/10.1021/acs.inorgchem.0c01618
Publikováno v:
Angewandte Chemie
We anticipate high-valent metal-fluoride species will be highly effective hydrogen atom transfer (HAT) oxidants because of the magnitude of the H-F bond (in the product) that drives HAT oxidation. We prepared a dimeric FeIII (F)-F-FeIII (F) complex (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0a703bd67cc592f5b82eef04b4330d38
https://pubmed.ncbi.nlm.nih.gov/34582619
https://pubmed.ncbi.nlm.nih.gov/34582619
Autor:
Adriana M. Magherusan, Subhasree Kal, Daniel N. Nelis, Lorna M. Doyle, Erik R. Farquhar, Lawrence Que, Aidan R. McDonald
Publikováno v:
Angewandte Chemie. 131:5774-5778
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4947d3551b551d84b369553a9f2b1009
https://doi.org/10.1002/ange.201900717
https://doi.org/10.1002/ange.201900717
Autor:
Adriana M, Magherusan, Subhasree, Kal, Daniel N, Nelis, Lorna M, Doyle, Erik R, Farquhar, Lawrence, Que, Aidan R, McDonald
Publikováno v:
Angewandte Chemie (International ed. in English). 58(17)
Ribonucleotide reductases (RNRs) are essential enzymes required for DNA synthesis. In class Ib Mn(2) RNRs superoxide (O(2)(•−)) was postulated to react with the Mn(II)(2) core to yield a Mn(II)Mn(III)-peroxide moiety. The reactivity of complex 1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::f4455d281575460172fb8e3e6537dba4
https://pubmed.ncbi.nlm.nih.gov/30830996
https://pubmed.ncbi.nlm.nih.gov/30830996
Autor:
Aidan R. McDonald, Erik R. Farquhar, Daniel N. Nelis, Lawrence Que, Subhasree Kal, Lorna M. Doyle, Adriana M. Magherusan
Publikováno v:
Angewandte Chemie International Edition
Ribonucleotide reductases (RNRs) are essential enzymes required for DNA synthesis. In class Ib Mn2 RNRs superoxide (O2 .- ) was postulated to react with the MnII 2 core to yield a MnII MnIII -peroxide moiety. The reactivity of complex 1 ([MnII 2 (O2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::369d8c471e6b1da206882c17e3fce102