Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Lois E. Nice"'
Publikováno v:
The Journal of Organic Chemistry. 70:2109-2119
[reaction: see text] Carbamate deprotonation followed by treatment with CuCN.2LiCl affords alpha-(N-carbamoyl)alkylcuprates which react with propargyl halides, mesylates, tosylates, phosphates, acetates, and epoxides to give alpha-(N-carbamoyl) allen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60d160dc8e31a54982529dd1bfc61483
https://doi.org/10.1021/jo0481405
https://doi.org/10.1021/jo0481405
Publikováno v:
The Journal of Organic Chemistry. 66:2302-2311
The effect of Cu(I) salt (i.e., CuCN, CuCN.2LiCl, CuI), cuprate reagent, sec-butyllithium quality, solvent, and temperature upon the chemical yields obtained in the reactions of alpha-(N-carbamoyl)alkylcuprates [i.e., N-Boc-protected alpha-aminoalkyl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e2ee078dfda454205b63ac69ba7a899b
https://doi.org/10.1021/jo0056702
https://doi.org/10.1021/jo0056702
Autor:
R. Karl Dieter, Lois E. Nice
Publikováno v:
Tetrahedron Letters. 40:4293-4296
α-Aminoalkylcuprates prepared from carbamates via sequential deprotonation and treatment with CuCN·2LiCl react with propargyl bromides, mesylates, tosylates, acetates, and epoxides to afford amino allenes via a SN2′ substitution process. Propargy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d765f25612253f6fea7250244a13ca1b
https://doi.org/10.1016/s0040-4039(99)00778-9
https://doi.org/10.1016/s0040-4039(99)00778-9
Publikováno v:
Tetrahedron Letters. 37:2377-2380
Mixtures of oxone and sodium chloride or sodium bromide afford solutions of chlorine or bromine, respectively. These solutions effectively add chlorine and bromine to α,β-enones and alkenes. The method affords improved yields of 3-alkyl-2-halo-2-cy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::829fbf2cb5bd299518e0109d22d6c1c8
https://doi.org/10.1016/0040-4039(96)00295-x
https://doi.org/10.1016/0040-4039(96)00295-x
Publikováno v:
Tetrahedron Letters. 35:57-60
Aldehydes and ketones can be converted to the corresponding p-methoxyphenylethylene acetals and ketals in good to excellent yield. Deprotection can be accomplished under mild conditions to produce uniformly excellent yields of the original carbonyl c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::73b4a1d1fb4b4d77ac5329bc96f9ac88
https://doi.org/10.1016/0040-4039(94)88161-8
https://doi.org/10.1016/0040-4039(94)88161-8
Publikováno v:
Tetrahedron Letters. 34:2741-2744
Primary aliphatic alcohols can be converted to methyl esters using calcium hypochlorite as the oxidant. Primary benzyl alcohols can also be converted efficiently to methyl benzoates.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5dede895470c59f7bc0d23a7ac5f7a69
https://doi.org/10.1016/s0040-4039(00)73550-7
https://doi.org/10.1016/s0040-4039(00)73550-7
Publikováno v:
ChemInform. 24
Primary aliphatic alcohols can be converted to methyl esters using calcium hypochlorite as the oxidant. Primary benzyl alcohols can also be converted efficiently to methyl benzoates.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a03eb6e5b96a9448c5cffdea1c4dbef6
https://doi.org/10.1002/chin.199339118
https://doi.org/10.1002/chin.199339118
Publikováno v:
ChemInform. 25
Aldehydes and ketones can be converted to the corresponding p-methoxyphenylethylene acetals and ketals in good to excellent yield. Deprotection can be accomplished under mild conditions to produce uniformly excellent yields of the original carbonyl c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fc71a1a5fa3d79c913cce187835849ed
https://doi.org/10.1002/chin.199417092
https://doi.org/10.1002/chin.199417092
Publikováno v:
ChemInform. 27
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::db68230b9afcf9d215415b06279d2fcf
https://doi.org/10.1002/chin.199632076
https://doi.org/10.1002/chin.199632076
Publikováno v:
ChemInform. 29
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e664d4bcdae1d958932ccaf230feedae
https://doi.org/10.1002/chin.199805064
https://doi.org/10.1002/chin.199805064