Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Loïc Mottier"'
Publikováno v:
Electrochimica Acta. 46:3237-3244
The oxidative addition of the allyl acetate CH 2 CHCH 2 OAc to the Pd 0 complex generated from [Pd 0 (dba) 2 ] and 2 equiv. PPh 3 (monodentate ligand) or 1 equiv. dppb (bidentate ligand) gives a cationic (η 3 -allyl)palladium(II) complex wi
Publikováno v:
Scopus-Elsevier
[Pd(η3-C3H5)(μ-Cl)]2 + 4PPh3 and [(η3-C3H5)PdCl(PPh3)] + 1PPh3 do not produce the cationic (π-allyl)palladium(II) complex [(η3-C3H5)Pd(PPh3)2]+Cl− but a neutral (σ-allyl)palladium(II) chloride complex [(η1-CH2=CH−CH2)PdCl(PPh3)2] in DMF an
Autor:
Francesco G. Gatti, Sergio Roffia, George W. H. Wurpel, Loïc Mottier, Francesco Paolucci, Albert M. Brouwer, David A. Leigh, Céline Frochot
Publikováno v:
Science, 291(5511), 2124-2128. American Association for the Advancement of Science
A rotaxane is described in which a macrocycle moves reversibly between two hydrogen-bonding stations after a nanosecond laser pulse. Observation of transient changes in the optical absorption spectrum after photoexcitation allows direct quantitative
Publikováno v:
Journal of The Electrochemical Society. 146:3357-3360
The electrochemistry of C 60 in tetrahydrofuran/tetrabutylammonium hexafluorophosphate (THF/TBAH) solutions was thoroughly investigated, and particular attention was devoted to possible interactions occurring between the fullerene and this medium and
Publikováno v:
European Journal of Inorganic Chemistry. 1999:1081-1085
Publikováno v:
Chemistry - A European Journal. 5:466-473
New insight into Pd-catalyzed allylic substitution: A cationic π-allylpalladium(II) complex is generated by the oxidative addition of allylic acetate to the palladium(0) complex generated from a mixture of Pd(dba)2+2 PPh3. This reaction is reversibl
Publikováno v:
Scopus-Elsevier
Within long times scales, the electrochemical oxidation of Pd(0)(PPh3)4 proceeds through an ECE-like two-electron process to afford two cationic palladium(II) complexes in equilibrium: Pd(II)(PPh3)2(BF4)2 and Pd(II)(PPh3)3(BF4)2, whose relative conce
Publikováno v:
Organometallics. 12:3168-3178
Publikováno v:
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 306:125-140
The mechanism of nickel-catalysed biaryl electrosynthesis from aromatic halides is shown to proceed through a reaction involving Ni(0), Ni(I), Ni(II) and Ni(III) intermediates. A detailed kinetic analysis of the propagation of the catalytic reaction
Autor:
Maurizio Carano, Loïc Mottier, Francesco Paolucci, Giovanni Ingrosso, Francesca Cicogna, Sergio Roffia, Julien L. Houben, Fabio Marchetti, C Pinzino
Publikováno v:
Inorganic chemistry. 41(13)
The anthryl-substituted rhodium(III) and iridium(III) heteroleptic beta-ketoenolato derivatives of general formula [M(acac)(2)(anCOacac)] [acac = pentane-2,4-dionate; anCOacac = 3-(9-anthroyl)pentane-2,4-dionate], 3 (M = Rh) and 4 (M = Ir), and [M(ac