Zobrazeno 1 - 10
of 129
pro vyhledávání: '"Liviu M. Mirica"'
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-11 (2023)
The characterization of nickel (Ni)‐centred paramagnetic states relevant to [NiFe] hydrogenases is rare in mononuclear Ni hydrogen evolution catalysts. Here, the authors report the spectroscopic and synthetic characterization of NiI and NiIII state
Externí odkaz:
https://doaj.org/article/b0635c6affef4863b82c3d175395f290
Autor:
Hanah Na, Liviu M. Mirica
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-11 (2022)
Mechanistic knowledge of photocatalytic nickel reactions is lacking, particularly with regards to the identities and oxidation states of key intermediates. Here the authors report a class of tridentate ligands that enables in-depth study of a represe
Externí odkaz:
https://doaj.org/article/0f90a35fa8f24b1483bf1473945545a1
Publikováno v:
Inorganics, Vol 11, Iss 11, p 446 (2023)
Two new ligands were synthesized with the goal of copper stabilization, N,N′-(2-methylpyridine)-2,11-diaza[3,3](2,6)pyridinophane (PicN4) and N-(methyl),N′-(2-methylpyridine)-2,11-diaza[3,3](2,6)pyridinophane (PicMeN4), by selective functionaliza
Externí odkaz:
https://doaj.org/article/2ef2cbae7cfd441688a63259d5ff0e87
Publikováno v:
Journal of the American Chemical Society. 145:11161-11172
Publikováno v:
Chemical Science. 14:3800-3808
Herein we report the direct observation of C–H bond activation at an isolated mononuclear Pd(iii) center.
Autor:
Karna Terpstra, Yujue Wang, Truc T. Huynh, Nilantha Bandara, Hong-Jun Cho, Buck E. Rogers, Liviu M. Mirica
Publikováno v:
Inorganic Chemistry. 61:20326-20336
Publikováno v:
Journal of the American Chemical Society. 144:20008-20015
Catalytic transformations involving Pd(0)/Pd(II) catalytic cycles are very well known, and processes involving high-valent Pd(III) and Pd(IV) and low-valent Pd(I) intermediates have also gained interest in recent years. Although low-valent Pd(I) inte
Publikováno v:
Organometallics. 41:2067-2076
Publikováno v:
ACS Omega. 7:20339-20346
Autor:
Yuting Wu, Seyed-Fakhreddin Torabi, Ryan J. Lake, Shanni Hong, Zhengxin Yu, Peiwen Wu, Zhenglin Yang, Kevin Nelson, Weijie Guo, Gregory T. Pawel, Jacqueline Van Stappen, Xiangli Shao, Liviu M. Mirica, Yi Lu
Publikováno v:
Science Advances. 9
Visualizing redox-active metal ions, such as Fe 2+ and Fe 3+ ions, are essential for understanding their roles in biological processes and human diseases. Despite the development of imaging probes and techniques, imaging both Fe 2+ and Fe 3+ simultan