Zobrazeno 1 - 2
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pro vyhledávání: '"Liujie Zhao"'
Publikováno v:
Organic Letters. 23:5901-5905
The de novo construction of axially chiral 3-arylindoles bearing a C(3)-C(aryl) chiral axis has been realized by Pd-catalyzed enantioselective Cacchi reaction between aryl bromides and o-alkynylanilines. The reaction proceeded under mild conditions i
Autor:
Yanliang Zhao, Liujie Zhao, Jierui Jing, Weiqiao Deng, Xue-Peng Zhang, Panjie Hu, Fen Wang, Xiaohan Zhu, Xingwei Li
Publikováno v:
Angewandte Chemie (International ed. in English). 60(30)
Reported herein is asymmetric [3+2] annulation of arylnitrones with different classes of alkynes catalyzed by chiral rhodium(III) complexes, with the nitrone acting as an electrophilic directing group. Three classes of chiral indenes/indenones have b