Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Lisa Vondung"'
Autor:
Christian Urbank, Lisa Vondung
Publikováno v:
Nachrichten aus der Chemie. 70:61-64
Publikováno v:
Organometallics. 41:1353-1363
We report the synthesis and characterization of uranium(IV) and thorium(IV) mesoionic carbene complexes [An{N(SiMe
Autor:
Ashley J. Wooles, Stephen T. Liddle, Lisa Vondung, Philip J. Cobb, Alexander J. Ayres, Peter A. Cleaves, John C. Stewart
Publikováno v:
Organometallics. 39:4735-4746
A series of Ni complexes [Ni(Cl)2(PR3)2] with R = Me (1-Me), nPr (1-nPr), and nBu (1-nBu) and nickelocenes [Ni(η5-C5H4R′)2] with R′ = H (2-H), Me (2-Me), and SiMe3 (2-SiMe3) were synthesized and ch...
Publikováno v:
Chemistry - A European Journal. 25:3068-3076
A systematic quantum chemical study of the bonding in d6 -transition-metal complexes, containing phosphine-stabilized, main-group-element fragments, (R3 P)2 E, as ligands (E=AlH, BH, CH+ , C), is reported. By using energy decomposition analysis, it i
Publikováno v:
Chemistry - A European Journal. 24:12346-12353
Easy-to-prepare η2 -coordinated phosphine-borane ligands are demonstrated to liberate hydrogen upon treatment with different σ-donor/π-acceptor ligands (CO, tBuNC, CN- ). Depending on the utilized ancillary ligand, different reaction pathways are
Publikováno v:
Polyhedron. 143:28-42
The platform of pincer ligands offers the opportunity to stabilize elusive groups in the coordination sphere of a metal. These groups often exhibit unusual bonding properties and can show unprecedented reactivity patterns, which are potentially usefu
Publikováno v:
Chemistry - A European Journal. 24:1358-1364
An iron pincer complex containing a hemi-labile (R₃P)₂BH₂-group exhibits temperature-switchable reactivity patterns: a reversible B-H-activation concomitant with a P-B-bond cleavage is observed at room temperature. Below 4 °C intra- and inter-
Publikováno v:
Chemical Communications. 53:7230-7233
We report a novel method for the preparation of PBP-pincer complexes from bis(phosphine)boronium salts. The central (R3P)2HB-moiety in a palladium complex is demonstrated to be a L-type ligand, therewith completing a series of pincer-type complexes w
Publikováno v:
Journal of the American Chemical Society. 141(18)
Unusual binding properties, enabling the stabilization of elusive species, and beneficial properties for homogeneous catalysts have been predicted and demonstrated for ligand-stabilized main group fragments, such as carbodiphosphoranes and -carbenes.
Publikováno v:
Angewandte Chemie International Edition. 55:14450-14454
Stabilized borylenes (L2 BH:) with weakly π-accepting substituents L, such as phosphines, were previously believed to be unstable. In the current manuscript, we describe a series of complexes formally containing a phosphine-stabilized borylene or bo