Lanthanide complexes (Gd$^{III}$ and Eu$^{III}$) based on a DOTA-TEMPO platform for redox monitoring via relaxivity

Autor: Richard Barré, Damien Mouchel dit Leguerrier, Quentin Ruet, Lionel Fedele, Daniel Imbert, Véronique Martel‐Frachet, Pascal H. Fries, Jennifer K. Molloy, Fabrice Thomas

Publikováno v: Chemistry-An Asian Journal
Chemistry-An Asian Journal, 2022, 17 (17), pp.e202200544. ⟨10.1002/asia.202200544⟩

International audience; Three lanthanide complexes (Ln=Gd, Eu) based on a DO3 A ([Ln(L$_1$)]) or DO2 A ([Ln(L$_{2-3}$)]$^+$) platform appended by a redox active TEMPO-based arm were prepared. Complex [Ln(L$_2$)]$^+$) shows an alkyne arm, offering the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c2c7210802e0fdd5a943889bde81593
https://hal.science/hal-03748496

Luminescent pro-nitroxide lanthanide complexes for the detection of reactive oxygen species

Autor: Fabrice Thomas, Daniel Imbert, Jennifer K. Molloy, Richard Barré, Lionel Fedele, Damien Mouchel dit Leguerrier

Publikováno v: Chemical Communications
Chemical Communications, Royal Society of Chemistry, 2020, 56 (3), pp.435-438. ⟨10.1039/c9cc06524e⟩
Chemical Communications, 2020, 56 (3), pp.435-438. ⟨10.1039/c9cc06524e⟩

International audience; The DOTA-based ligand H3L (5) appended with a pro-nitroxide moiety has been synthesized. The europium and ytterbium complexes 5Ln show metal-centred luminescence. They react with ROS in aqueous media to give a transient iminon

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::abbb15f99fbb0c5a5285311e1d5bea0f
https://hal.archives-ouvertes.fr/hal-02874020/document

Seven-coordinate lanthanide complexes with a tripodal redox active ligand: structural, electrochemical and spectroscopic investigations

Autor: Christian Philouze, Olivier Jarjayes, Jennifer K. Molloy, Fabrice Thomas, Lionel Fedele, Daniel Imbert

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2018, 47 (31), pp.10742-10751. ⟨10.1039/c8dt01165f⟩
Dalton Transactions, 2018, 47 (31), pp.10742-10751. ⟨10.1039/c8dt01165f⟩
Dalton Transactions, Royal Society of Chemistry, 2018, 47 (31), pp.10742-10751

The tripodal ligand TREN-(3,5-di-tert-butylsalicylidene)3 (H3L) was synthesized and its tris(phenolato) lanthanide complexes L-Ln (Ln = NdIII, EuIII, TbIII, GdIII, ErIII, YbIII and LuIII) were prepared. The X-Ray crystal structures confirm that each

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f5bc40ced9ce6b3daaf37c76ff3c526f
https://hal.archives-ouvertes.fr/hal-01847112