Some unusual reactivities in the SmI 2-mediated reductive coupling of acrylamides and acrylates with imides

Autor: Taaning, Rolf H., Lindsay, Karl B., Skrydstrup, Troels

Publikováno v: In Tetrahedron 2009 65(52):10908-10916

Importance of C-N bond rotation in N-acyl oxazolidinones in their SmI2-promoted coupling to acrylamides

Autor: Taaning, Rolf H, Lindsay, Karl B, Schiøtt, Birgit, Daasbjerg, Kim, Skrydstrup, Troels, Taaning, Rolf Hejle

Publikováno v: Taaning, R H, Lindsay, K B, Schiøtt, B, Daasbjerg, K, Skrydstrup, T & Taaning, R H 2009, ' Importance of C-N bond rotation in N-acyl oxazolidinones in their SmI2-promoted coupling to acrylamides ', Journal of the American Chemical Society, vol. 131, no. 29, pp. 10253-62 . https://doi.org/10.1021/ja903401y

A detailed mechanistic investigation was undertaken to determine the dominating factors of the postelectron transfer steps in the SmI(2)-promoted carbon-carbon bond forming reaction between N-acyl oxazolidinones and acrylamides. Competition experimen

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cb4e12c1623227c3b9a0a3aacdccfbcf
https://pure.au.dk/portal/da/publications/importance-of-cn-bond-rotation-in-nacyl-oxazolidinones-in-their-smi2promoted-coupling-to-acrylamides(c673aa19-eeed-45de-a5aa-e6e5289102ae).html

C-N Bond Rotation in N-Acyl Oxazolidinones as the Controlling Factor in Their SmI2-Promoted Coupling to Acrylamides

Autor: Taaning, Rolf Hejle, Lindsay, Karl, Schiøtt, Hanne Birgit, Daasbjerg, Kim, Skrydstrup, Troels

Publikováno v: Taaning, R H, Lindsay, K, Schiøtt, H B, Daasbjerg, K & Skrydstrup, T 2009, ' C-N Bond Rotation in N-Acyl Oxazolidinones as the Controlling Factor in Their SmI 2-Promoted Coupling to Acrylamides ', Journal of the American Chemical Society, vol. 131, pp. 10253-10262 .

Udgivelsesdato: 2009

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pure_au_____::abd8c427cae26d807b45402d8ed1f36f
https://pure.au.dk/portal/da/publications/cn-bond-rotation-in-nacyl-oxazolidinones-as-the-controlling-factor-in-their-smi2promoted-coupling-to-acrylamides(35b39ec0-9c59-11de-a092-000ea68e967b).html

Synthesis of Silanediol Peptide Mimics

Autor: Nielsen, Lone, Lindsay, Karl, Skrydstrup, Troels

Publikováno v: Nielsen, L, Lindsay, K & Skrydstrup, T 2008, ' Synthesis of Silanediol Peptide Mimics ', Dublin, Ireland, 08/07/2007-13/07/2007, .

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pure_au_____::f3f64953862d62ce385a6641f845c0a3
https://pure.au.dk/portal/da/publications/synthesis-of-silanediol-peptide-mimics(fb669970-ce46-11dc-abe4-000ea68e967b).html

Creating carbon-carbon bonds with samarium diiodide for the synthesis of modified amino acids and peptides

Autor: Ebran, Jean-Philippe, Jensen, Christina M, Johannesen, Sine A, Karaffa, Jakob, Lindsay, Karl B, Taaning, Rolf, Skrydstrup, Troels, Taaning, Rolf Hejle

Publikováno v: Ebran, J-P, Jensen, C M, Johannesen, S A, Karaffa, J, Lindsay, K B, Taaning, R, Skrydstrup, T & Taaning, R H 2006, ' Creating carbon-carbon bonds with samarium diiodide for the synthesis of modified amino acids and peptides ', Organic & Biomolecular Chemistry, vol. 4, no. 19, pp. 3553-64 . https://doi.org/10.1039/b608028f

In this perspective, an overview of our experiences on the application of samarium diiodide in organic synthesis for the preparation of amino acid and peptide analogues is presented. Three different carbon-carbon bond forming reactions are discussed,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::73fc5d3eee3b3ddef351785afa27974c
https://pubmed.ncbi.nlm.nih.gov/16990928