Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Lia, Sotorrios"'
Autor:
Matthew P. Stevens, Emily Spray, Iñigo J. Vitorica-Yrezabal, Kuldip Singh, Vanessa M. Timmermann, Lia Sotorrios, Fabrizio Ortu
Publikováno v:
Molecules, Vol 27, Iss 14, p 4564 (2022)
Herein, we report the synthesis of a series of heteroleptic magnesium complexes stabilized with the scorpionate ligand tris(2-pyridylthio)methanide (Tptm). The compounds of the general formula [Mg(Tptm)(X)] (1-X; X = Cl, Br, I) were obtained via prot
Externí odkaz:
https://doaj.org/article/8da74247be4e4346bb5646832d0ddb43
Autor:
Matthew E. Grundy, Lia Sotorrios, Milan Kumar Bisai, Kang Yuan, Stuart A. Macgregor, Michael J. Ingleson
Publikováno v:
Grundy, M E, Sotorrios, L, Bisai, M K, Yuan, K, Macgregor, S A & Ingleson, M J 2023, ' Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C-H Borylation ', ACS Catalysis, pp. 2286-2294 . https://doi.org/10.1021/acscatal.2c05995
[(NacNac)Zn(DMT)][B(C6F5)4], 1, (NacNac = {(2,6-iPr2H3C6)N(CH3)C}2CH), DMT = N,N-dimethyl-4-toluidine), was synthesized via two routes starting from either (NacNac)ZnEt or (NacNac)ZnH. Complex 1 is an effective (pre)catalyst for the C-H borylation of
Publikováno v:
ACS Catalysis. 12:13050-13064
Autor:
Matthew P. Stevens, Emily Spray, Iñigo J. Vitorica-Yrezabal, Kuldip Singh, Vanessa M. Timmermann, Lia Sotorrios, Stuart A. Macgregor, Fabrizio Ortu
Publikováno v:
Dalton Transactions. 51:11922-11936
Group 2 organometallics were synthesised with a thiopyridyl scorpionate ligand and were tested for their catalytic activity in hydrophosphination reactions. Kinetic studies and DFT calculations were also used to elucidate degradation pathways.
Publikováno v:
ACS catalysis. 12(20)
The dehydropolymerization of H
Autor:
Cameron G, Royle, Lia, Sotorrios, Matthew R, Gyton, Claire N, Brodie, Arron L, Burnage, Samantha K, Furfari, Anna, Marini, Mark R, Warren, Stuart A, Macgregor, Andrew S, Weller
Publikováno v:
Organometallics. 41(22)
The reactivity of the Ir(I) PONOP pincer complex [Ir(
Autor:
Lia Sotorrios, Fedor M. Miloserdov, Anne‐Frédérique Pécharman, John P. Lowe, Stuart A. Macgregor, Mary F. Mahon, Michael K. Whittlesey
Publikováno v:
Angewandte Chemie-International Edition 61 (2022) 19
Angewandte Chemie-International Edition, 61(19)
Angewandte Chemie-International Edition, 61(19)
The syntheses, reactivity and electronic structure analyses of [Ru(PPh3)2(ZnMe)4H2], 1 a, and [Ru(PPh3)2(ZnPh)4H2], 2 b, are reported. 1 a exhibits an 8-coordinate Ru centre with axial phosphines and a symmetrical (2 : 2) arrangement of ZnMe ligands
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0beb6d9d4c710d0c4a0c5c5e05f88f1b
https://research.wur.nl/en/publications/zinc-promoted-znmeznph-exchange-in-eight-coordinate-rupphsub3subs
https://research.wur.nl/en/publications/zinc-promoted-znmeznph-exchange-in-eight-coordinate-rupphsub3subs
Autor:
Lia, Sotorrios, Fedor M, Miloserdov, Anne-Frédérique, Pécharman, John P, Lowe, Stuart A, Macgregor, Mary F, Mahon, Michael K, Whittlesey
Publikováno v:
Angewandte Chemie (International ed. in English). 61(19)
The syntheses, reactivity and electronic structure analyses of [Ru(PPh
Autor:
Fedor M, Miloserdov, Anne-Frédérique, Pécharman, Lia, Sotorrios, Nasir A, Rajabi, John P, Lowe, Stuart A, Macgregor, Mary F, Mahon, Michael K, Whittlesey
Publikováno v:
Inorganic Chemistry
A combined experimental and computational study of the structure and reactivity of two [RuZn2Me2] complexes, neutral [Ru(PPh3)(Ph2PC6H4)2(ZnMe)2] (2) and cationic [Ru(PPh3)2(Ph2PC6H4)(ZnMe)2][BArF4] ([BArF4] = [B{3,5-(CF3)2C6H3}4]) (3), is presented.