Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Levy L, Cao"'
Autor:
Jingjie Tan, Chaopeng Hu, Xin Yang, Shaoying Ju, Levy L. Cao, Yile Wu, Liu Leo Liu, Douglas W. Stephan
Publikováno v:
Chemical Communications. 59:282-285
The aluminum analogue of Piers’ borane, [HAl(C6F5)2]3, is prepared on a gram-scale and shown to be highly acidic, a strong hydride donor, and a catalysts for the hydrosilylation of alkynes and alkenes.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3c8d8f3a511d68c8556f827b4583464a
https://doi.org/10.1039/d2cc06075b
https://doi.org/10.1039/d2cc06075b
Publikováno v:
Chemical Communications. 56:12953-12956
Double chloride abstraction from Cp*SbCl2 (Cp* = pentamethylcyclopentadienyl) affords an arene-stabilized η5-Cp*-bound antimony dicationic compound [(η5-Cp*)Sb(tol)][B(C6F5)4]2 (1) (tol = toluene), which exhibits strong Lewis acidity, abstracting c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6a5c7c26bf2afcfc4418e342981ebf98
https://doi.org/10.1039/d0cc02710c
https://doi.org/10.1039/d0cc02710c
Publikováno v:
Angewandte Chemie. 131:18444-18448
The salts [(BAC)2 PO][BF4 ] (5) and [(BAC)2 PO2 ][BF4 ] (4) (BAC=bis(diisopropylamino) cyclopropenylidene), consisting of the PO+ and PO2 + cations, respectively, coordinated to the singlet carbenes, have been prepared. Computational investigations r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e3715fba61de1b2e125478f9590a628e
https://doi.org/10.1002/ange.201912009
https://doi.org/10.1002/ange.201912009
Publikováno v:
Angewandte Chemie (International Ed. in English)
While (Ph2CN2)B(C6F5)3 is unstable, single electron transfer from Cp*2Co affords the isolation of stable products [Cp*2Co][Ph2CNNHB(C6F5)3] 1 and [Cp*Co(C5Me4CH2B(C6F5)3)] 2. The analogous combination of Ph2CN2 and BPh3 showed no evidence of adduct f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6529418e75d98aeef0e9abd72b871990
https://doi.org/10.1002/anie.201912338
https://doi.org/10.1002/anie.201912338
Publikováno v:
Angewandte Chemie. 131:5461-5466
Double chloride abstraction of Cp*AsCl2 gives the dicationic arsenic species [(η5 -Cp*)As(tol)][B(C6 F5 )4 ]2 (2) (tol=toluene). This species is shown to exhibit Lewis super acidity by the Gutmann-Beckett test and by fluoride abstraction from [NBu4
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8379c014b88765285b84bfc8d8b6971c
https://doi.org/10.1002/ange.201902039
https://doi.org/10.1002/ange.201902039
Publikováno v:
Chemical communications (Cambridge, England). 56(85)
Double chloride abstraction from Cp*SbCl2 (Cp* = pentamethylcyclopentadienyl) affords an arene-stabilized η5-Cp*-bound antimony dicationic compound [(η5-Cp*)Sb(tol)][B(C6F5)4]2 (1) (tol = toluene), which exhibits strong Lewis acidity, abstracting c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::43e9491f00b4ad472766cb4a29f33975
https://pubmed.ncbi.nlm.nih.gov/32985631
https://pubmed.ncbi.nlm.nih.gov/32985631
Publikováno v:
Chem. 4:2699-2708
Summary Abstraction of chloride from (Cp*PCl2) with the silylium salt [Et3Si][B(C6F5)4] afforded [(η2-Cp*)PCl][B(C6F5)4] (1), whereas further chloride abstraction using another equivalent [Et3Si][B(C6F5)4] was unsuccessful. The corresponding species
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1650b1159fe8b406b05540756bf832c8
https://doi.org/10.1016/j.chempr.2018.08.038
https://doi.org/10.1016/j.chempr.2018.08.038
Publikováno v:
Chemistry - A European Journal. 24:8589-8595
The reductive coupling of two diazomethanes is affected by reaction with [(NacNacMes )Mg]2 affording the species [(NacNacMes )Mg(N2 CPh2 )]2 2 and [(NacNacMes )Mg(N2 C(C6 H4 )2 )]2 3. These species containing N4 linkages readily evolve the central N2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::45def1d934874abf6f0942d62b5e6981
https://doi.org/10.1002/chem.201802138
https://doi.org/10.1002/chem.201802138
Publikováno v:
Angewandte Chemie. 130:3380-3384
A room-temperature-stable crystalline cyclic (alkyl)(amino)nitrenium cation 2 features cationic nitrogen atom with a smaller HOMO-LUMO gap compared to that of a 1,2,3-triazolium 5 (an N-heterocyclic nitrenium cation). The low-lying LUMO of 2 results
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00045a4e551374ba0895db6d1afdc5e9
https://doi.org/10.1002/ange.201713118
https://doi.org/10.1002/ange.201713118
Autor:
Douglas W. Stephan, Levy L. Cao
Publikováno v:
Chemical Communications. 54:8407-8410
Varying the reaction ratio of cyclic (alkyl)(amino) carbene (cAACEt) with AlH3·NEtMe2 leads to the isolation of (cAACEtH)AlH2·NEtMe21 and (cAACEtH)2Al(μ-H)2AlH2·NEtMe22 and the first example of a monomeric dialkyl-aluminum hydride (cAACEtH)2AlH 3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::53212bd9988e9c66b1064b2eb4ca7489
https://doi.org/10.1039/c8cc05013a
https://doi.org/10.1039/c8cc05013a